Synthesis of azidopropargylamino-substituted 1,3,5-triazines - novel monomers for the production of energetic polymers

被引：3

作者：

Shastin, Aleksey V. ^{[1
]}

Petrov, Artem O. ^{[1
]}

Malkov, Georgiy V. ^{[1
]}

Gavrishova, Tatiana N. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, 1 Akad Semenova Ave, Chernogolovka 142432, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2021年 / 57卷 / 7-8期

关键词：

azides; propargylamine; 1,3,5-triazines; azidation; nitrosation; DENDRIMERS; DERIVATIVES;

D O I：

10.1007/s10593-021-02993-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Efficient methods for the synthesis of novel azidopropargylamino-substituted 1,3,5-triazines were developed. 4,6-Diazido-N-(prop-2-yn-1-yl)-1,3,5-triazin-2-amine was obtained by the method of sequential nucleophilic substitution of chlorine atoms in cyanuric chloride by amino and azido groups or by the method of selective substitution of the azido group in triazidotriazine with propargylamine. 6-Azido-N-2,N-4-dimethyl-N-2,N-4-di(prop-2-yn-1-yl)-1,3,5-triazine-2,4-diamine was obtained by nitrosation of the corresponding 6-hydrazinyl-N-2,N-4-dimethyl-N-2,N-4-di(prop-2-yn-1-yl)-1,3,5-triazine-2,4-diamine. Monomers with a lower melting point were obtained by N-methylation of azidopropargylamino-substituted 1,3,5-triazines.

引用

页码：866 / 870

页数：5

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