Single-Molecule Imaging of Platinum Ligand Exchange Reaction Reveals Reactivity Distribution

被引：36

作者：

Esfandiari, N. Melody ^{[1
]}

Wang, Yong ^{[1
]}

Bass, Jonathan Y. ^{[1
]}

Cornell, Trevor P. ^{[1
]}

Otte, Douglas A. L. ^{[1
]}

Cheng, Ming H. ^{[1
]}

Hemminger, John C. ^{[1
]}

McIntire, Theresa M. ^{[1
]}

Mandelshtam, Vladimir A. ^{[1
]}

Blum, Suzanne A. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 43期

关键词：

REFLECTION FLUORESCENCE MICROSCOPY; METAL-COMPLEXES; HIGH-RESOLUTION; SPECTROSCOPY; SILANIZATION; DIFFUSION; LINKERS; PROBES;

D O I：

10.1021/ja105517d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-molecule fluorescence microscopy provided information about the real-time distribution of chemical reactivity on silicon oxide supports at the solution surface interface, at a level of detail which would be unavailable from a traditional ensemble technique or from a technique that imaged the static physical properties of the surface. Chemical reactions on the surface were found to be uncorrelated; that is, the chemical reaction of one metal complex did not influence the location of a future chemical reaction of another metal complex.

引用

页码：15167 / 15169

页数：3

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