New magnetically recoverable palladium-based catalysts active in the alkoxycarbonylation of iodobenzene

被引：7

作者：

Vavasori, Andrea ^{[1
]}

Calgaro, Loris ^{[1
]}

Quartarone, Giuseppe ^{[1
]}

Ronchin, Lucio ^{[1
]}

Tortato, Claudio ^{[1
]}

机构：

[1] Ca Foscari Univ Venice, Dept Mol Sci & Nanosyst, Via Torino 155, I-30172 Mestre Venezia, Italy

来源：

PURE AND APPLIED CHEMISTRY | 2016年 / 88卷 / 05期

关键词：

carbonylation; Green Chemistry V; heterogeneous catalysis; magnetic properties; palladium catalysis; ARYL HALIDES; CARBONYLATION REACTIONS; CARBON-MONOXIDE; HETEROGENEOUS CATALYSIS; ATMOSPHERIC-PRESSURE; COUPLING REACTIONS; SUZUKI-MIYAURA; IONIC LIQUIDS; COPOLYMERIZATION; NANOPARTICLES;

D O I：

10.1515/pac-2016-0204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New magnetically recoverable catalysts have been synthesized by deposition of 1 % palladium (Pd)metal on the polymer poly(1-oxo-trimethylene), containing 15 % of magnetite. The magnetite allows the complete recovery of the catalyst with the simple application of an external magnetic field. The activity of such a catalyst has been studied under phosphine-free conditions in the alkoxycarbonylation of iodobenzene to the corresponding benzoic acid esters.

引用

页码：445 / 455

页数：11

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