Optical Thin Film Sensing of Metal Ions Based on a New Chromogenic Calix[4]arene Derivative

被引：4

作者：

Ebdelli, R. ^{[1
,2
]}

Rouis, A. ^{[1
]}

Davenas, J. ^{[2
]}

Bonnamour, I. ^{[3
]}

Ben Ouada, H. ^{[1
]}

机构：

[1] Fac Sci Monastir, Lab Phys & Chim Interfaces, Monastir 5000, Tunisia

[2] Univ Lyon 1, CNRS, UMR 5223, F-69622 Villeurbanne, France

[3] Univ Lyon 1, CNRS, UMR, ICBMS, F-69622 Villeurbanne, France

来源：

SENSOR LETTERS | 2011年 / 9卷 / 06期

关键词：

Azo-Calix[4]arene; Complexation; Optical Thin Film Sensor; Thin Film; Fluorescence; ABSORPTION-SPECTRA; RECOGNITION; SENSORS; AZOCALIXARENES; CALIXARENES; EXTRACTION; SWITCHES;

D O I：

10.1166/sl.2011.1779

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The development of sensors to detect transition metal ions is a matter of special attention because of their toxic impact on our environment. A new chromogenic calix[4]arene derivative has been investigated combining the high recognition properties of calixarenes functionalized by an ester group and the optical response of an azo-group. The complexing properties of the tetrakis-(phenylazo)calix[4]arene derivative thin films have been studied by UV-Vis spectrophotometry. The sensing properties of the calix[4]arene thin films have been characterized in a second step by fluorescence spectroscopy. Main changes in the absorption spectrum so as in the fluorescence response are shown upon complexation of metallic and lanthanide cations, providing an easy and sensitive tool to detect main pollutants.

引用

页码：2241 / 2244

页数：4

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