Do heavy nuclei see light at the end of the tunnel?

被引：4
作者：
Berger, R [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 04期
关键词：
carbenes; density functional calculations; IR spectroscopy; matrix isolation; tunneling;
D O I：
10.1002/anie.200301675
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The direct route. Low-temperature experiments and calculations on the ring expansion of (1-methylcyclobutyl)fluorocarbene, which involves considerable movement of the heavy nuclei, indicate that tunneling through the barrier is more favorable than the classical route over the mountain pass" (see picture)."
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收藏
页码：398 / 401
页数：4
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