TEMPO-modified graphite felt electrodes:: attempted enantioselective oxidation of rac-1-phenylethanol in the presence of (-)-sparteine

被引：15
作者：
Belgsir, EM
Schäfer, HJ
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
[2] Univ Poitiers, Catalyse Chim Organ Lab, CNRS, UMR N6503, F-86022 Poitiers, France
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 05期
关键词：
D O I：
10.1039/a809789e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
At a TEMPO-modified graphite felt electrode (TMGFE) rac-1-phenylethanol 2 is not enantioselectively oxidised in the presence of(-)-sparteine 1, but instead 1 is dehydrogenated to its iminium salt; 2 is oxidised in solution by the oxoammonium salt 6 in the absence of 1, but not on the TMGFE in the range 0-1.0 V vs, Ag/AgNO3.
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页码：435 / 436
页数：2
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