Hydrogen-bonded supramolecular structures constructed from trinuclear copper units

被引：6
|
作者：
Qin, Su-Ni [1 ,2 ]
Huang, Hai-Ming [1 ]
Chen, Zi-Lu [1 ]
Liang, Fu-Pei [1 ]
机构：
[1] Guangxi Normal Univ, Sch Chem & Chem Engn, Key Lab Chem & Mol Engn Med Resources, Minist Educ China, Guilin 541004, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2011年 / 36卷 / 06期
基金：
中国国家自然科学基金;
关键词：
COORDINATION POLYMERS; CRYSTAL-STRUCTURES; COMPLEXES; LIGANDS; SERIES; DINUCLEAR; NETWORK;
D O I：
10.1007/s11243-011-9515-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four copper complexes with similar trinuclear copper units, [Cu-6(Bmshp)(2)(SO4)(2)(H2O)(7)]center dot 2H(2)O (1), [Cu-3(Bmshp)(ClO4)(2)(H2O)(4)]center dot 5H(2)O (2), [Cu-3(Bmshp)(DMF)(4)(H2O)(2)]center dot H2O center dot 2DMF center dot 2ClO(4) (3) and [Cu-3(H(2)Bcshp)(ClO4)(2)(H2O)(4)]center dot 3H(2)O (4) (H(4)Bmshp = 2,6-bis[(3-methoxysalicylidene)hydrazinocarbonyl]pyridine, H(6)Bcshp = 2,6-bis[(3-carboxylsalicylidene)hydrazinocarbonyl]pyridine), were synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction analysis. Due to the different anions, solvents and ligands used in the syntheses, complexes 1-4 exhibit diverse supramolecular structures constructed from the corresponding trinuclear copper units via H-bonds.
引用
收藏
页码：653 / 662
页数：10
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