A Series of 19′-Hexanoyloxyfucoxanthin Derivatives from the Sea Mussel, Mytilus galloprovincialis, Grown in the Black Sea, Ukraine

被引:16
作者
Maoka, Takashi [1 ]
Etoh, Tetsuji [2 ]
Borodina, Alexandra V. [3 ]
Sodatov, Alexander A. [3 ]
机构
[1] Res Inst Prod Dev, Sakyo Ku, Kyoto 6060805, Japan
[2] Kyoto Univ, Grad Sch Pharmaceut Sci, Sakyo Ku, Kyoto 6068501, Japan
[3] AO Kovalevsky Natl Acad Sci Ukraine, Inst Biol So Seas, UA-99011 Sevastopol, Crimea, Ukraine
关键词
Carotenoids; sea mussel; Mytilus galloprovincialis; 19-or 19 '-hexanoyloxy carotenoids; MARINE CAROTENOIDS; FUCOXANTHIN; HALOCYNTHIAXANTHIN; EXPRESSION; CELLS; CLAM;
D O I
10.1021/jf2035115
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
A series of carotenoids with 19- or 19'-hexanoyloxy moieties, 19'-hexanoyloxyfucoxanthin (1), 19'-hexanoyloxyfucoxanthinol (2), 19'-hexanoyloxyhalocynthiaxanthin (3), 19-hexanoyloxycrassostreaxanthin A (4), 19-hexanoyloxymytiloxanthin (5), and 19-hexanoyloxyallenicmytiloxanthin (6) were isolated from the edible part of the sea mussel, Mytilus galloprovincialis, grown in the Black Sea, Ukraine. Among them, 3, 4, and 6 were new compounds. These structures were charcterized by UV-vis, fast atom bombardment mass spectrometry, circular dichroism, and H-1 NMR spectroscopic data. They were assumed to be metabolites of 19'-hexanoyloxyfucoxanthin (1).
引用
收藏
页码:13059 / 13064
页数:6
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