High temperature oxidation of γ/γ′-strengthened Co-base superalloys

被引:184
作者
Klein, L. [1 ]
Bauer, A. [2 ]
Neumeier, S. [2 ]
Goeken, M. [2 ]
Virtanen, S. [1 ]
机构
[1] Univ Erlangen Nurnberg, Dept Mat Sci & Engn, Inst Surface Sci & Corros WW4, D-91058 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Dept Mat Sci & Engn, Inst Gen Mat Properties WW1, D-91058 Erlangen, Germany
关键词
Alumina; Boron; Co-base superalloy; High-temperature oxidation; Oxide layer; BORON; ALLOYS;
D O I
10.1016/j.corsci.2011.02.033
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Isothermal oxidation was carried out on new gamma/gamma ' Co-base superalloys of the system Co-Al-W-B. Appropriate B-contents lead to improved oxidation resistance and oxide layer adhesion. Oxidation at 800 and 900 degrees C results in formation of Co3O4, CoO, and complex oxides (containing Co, Al, and W). A continuous and protective inner alumina layer forms only at 800 degrees C. Furthermore, oxidation leads to phase transformation (gamma/gamma ' to gamma/Co3W microstructure) at the matrix/oxide layer interface due to Al-depletion. The effect of additional alloying elements such as Ta, Cr, Nb, Si, V. Mo, and It on the oxidation behaviour was also investigated. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2027 / 2034
页数:8
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