From Metal-Organic Framework to Nanoporous Carbon: Toward a Very High Surface Area and Hydrogen Uptake

被引：1078

作者：

Jiang, Hai-Long ^{[1
]}

Liu, Bo ^{[1
]}

Lan, Ya-Qian ^{[1
]}

Kuratani, Kentaro ^{[1
]}

Akita, Tomoki ^{[1
]}

Shioyama, Hiroshi ^{[1
]}

Zong, Fengqi ^{[2
]}

Xu, Qiang ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan

[2] Changzhou Univ, Analyt & Testing Ctr, Changzhou, Jiangsu, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 31期

关键词：

TEMPLATED MESOPOROUS CARBONS; CARBIDE-DERIVED CARBONS; STORAGE CAPACITY; SEPARATION; POROSITY; ACID;

D O I：

10.1021/ja203184k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, with a zeolite-type metal organic framework as both a precursor and a template and furfuryl alcohol as a second precursor, nanoporous carbon material has been prepared with an unexpectedly high surface area (3405 m(2)/g, BET method) and considerable hydrogen storage capacity (2.77 wt % at 77 K and 1 atm) as well as good electrochemical properties as an electrode material for electric double layer capacitors. The pore structure and surface area of the resultant carbon materials can be tuned simply by changing the calcination temperature.

引用

页码：11854 / 11857

页数：4

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