MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers chemiresistor and their application in low molecular weight alcohol vapours sensing

被引:31
作者
Choi, Jaewon [1 ]
Park, Eun Joo [1 ]
Park, Dong Wha [1 ]
Shim, Sang Eun [1 ]
机构
[1] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
关键词
Chemical vapour sensor; Nylon 6,6; MWCNT; Electrospinning; Nanofiber; MULTIWALLED CARBON NANOTUBES; POLYMER-SOLUTIONS; SENSORS; GAS; TRANSPARENT; COMPOSITES; MEMBRANES; STORAGE; BLENDS; FILMS;
D O I
10.1016/j.synthmet.2010.10.022
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Herein, we fabricated MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by electrospinning and dip coating method. The amount of MWCNT-OH adsorbed to the pure electrospun nylon 6,6 nanofibers was 0.056 Mt. The electrical conductivity of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers was 5.24 x 10(-3) S cm(-1). We also investigated the sensing properties of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers by measuring its response upon exposure to low molecular weight alcohol vapours such as methanol, ethanol, 1-propanol, and 1-butanol. The changes of the electrical resistance of MWCNT-OH adsorbed electrospun nylon 6,6 nanofibers were demonstrated on the basis of hydrogen bonds among the alcohol vapours and hydroxyl groups (-OH) on MWCNT-OH, and amide groups (-NHCO-) in nylon 6,6. The fabricated sensor showed good reversible and reproducible responses upon the cyclic test. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2664 / 2669
页数:6
相关论文
共 34 条
[1]   Logic circuits with carbon nanotube transistors [J].
Bachtold, A ;
Hadley, P ;
Nakanishi, T ;
Dekker, C .
SCIENCE, 2001, 294 (5545) :1317-1320
[2]   Carbon nanotube actuators [J].
Baughman, RH ;
Cui, CX ;
Zakhidov, AA ;
Iqbal, Z ;
Barisci, JN ;
Spinks, GM ;
Wallace, GG ;
Mazzoldi, A ;
De Rossi, D ;
Rinzler, AG ;
Jaschinski, O ;
Roth, S ;
Kertesz, M .
SCIENCE, 1999, 284 (5418) :1340-1344
[3]   Carbon nanotubes/poly(ε-caprolactone) composite vapour sensors [J].
Castro, Mickael ;
Lu, Jianbo ;
Bruzaud, Stephane ;
Kumar, Bijandra ;
Feller, Jean-Francois .
CARBON, 2009, 47 (08) :1930-1942
[4]   The fabrication of a MWNTs-polymer composite chemoresistive sensor array to discriminate between chemical toxic agents [J].
Chang, Chang-Pin ;
Yuan, Chun-Lung .
JOURNAL OF MATERIALS SCIENCE, 2009, 44 (20) :5485-5493
[5]   Carbon nanotubule membranes for electrochemical energy storage and production [J].
Che, GL ;
Lakshmi, BB ;
Fisher, ER ;
Martin, CR .
NATURE, 1998, 393 (6683) :346-349
[6]   Chain confinement in electrospun nanofibers of PET with carbon nanotubes [J].
Chen, Huipeng ;
Liu, Zhen ;
Cebe, Peggy .
POLYMER, 2009, 50 (03) :872-880
[7]   Purification of carbon nanotubes [J].
Hou, Peng-Xiang ;
Liu, Chang ;
Cheng, Hui-Ming .
CARBON, 2008, 46 (15) :2003-2025
[8]  
Incarnato L, 1999, J POLYM SCI POL PHYS, V37, P2445, DOI 10.1002/(SICI)1099-0488(19990901)37:17<2445::AID-POLB16>3.0.CO
[9]  
2-J
[10]   Printed multilayer superstructures of aligned single-walled carbon nanotubes for electronic, applications [J].
Kang, Seong Jun ;
Kocabas, Coskun ;
Kim, Hoon-Sik ;
Cao, Qing ;
Meitl, Matthew A. ;
Khang, Dahl-Young ;
Rogers, John A. .
NANO LETTERS, 2007, 7 (11) :3343-3348