Fluorescence emission originated from the H-aggregated cyanine dye with chiral gemini surfactant assemblies having a narrow absorption band and a remarkably large Stokes shift

被引：51

作者：

Ryu, Naoya ^{[1
,2
]}

Okazaki, Yutaka ^{[3
,4
]}

Pouget, Emilie ^{[4
]}

Takafuji, Makoto ^{[2
,3
]}

Nagaoka, Shoji ^{[1
,2
,3
]}

Ihara, Hirotaka ^{[2
,3
]}

Oda, Reiko ^{[4
]}

机构：

[1] Kumamoto Ind Res Inst, Mat Dev Dept, Higashi Ku, 3-11-38 Higashimachi, Kumamoto 8620901, Japan

[2] Kumamoto Inst Photoelect Organ PHOENICS, Higashi Ku, 3-11-38 Higashimachi, Kumamoto 8620901, Japan

[3] Kumamoto Univ, Dept Appl Chem & Biochem, Chuo Ku, 2-39-1 Kurokami, Kumamoto 8608555, Japan

[4] Univ Bordeaux, Inst Chem & Biol Membranes & Nanoobjects UMR5248, CNRS, Inst Polytech Bordeaux, 2 Rue Robert Escarpit, F-33607 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 63期

基金：

日本学术振兴会;

关键词：

MODULATION; EXCITON; DIMERS; STATE;

D O I：

10.1039/c7cc04484d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate that the fluorescence emission that originated from a cyanine dye forming H-aggregates with a narrow absorption band and a remarkably large Stokes shift can be induced by symmetry breaking. The H-aggregate formation was successfully induced using chirally assembled cationic gemini surfactants with enantiomeric tartrate counterions as templates in water.

引用

收藏

页码：8870 / 8873

页数：4

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