Synthesis and crystal structures of non-symmetric 1,3-di(alkyloxy)imidazolium salts

被引：10

作者：

Jochriem, Markus ^{[1
]}

Kirchler, Christian G. ^{[1
]}

Laus, Gerhard ^{[1
]}

Wurst, Klaus ^{[1
]}

Kopacka, Holger ^{[1
]}

Mueller, Thomas ^{[1
]}

Schottenberger, Herwig ^{[1
]}

机构：

[1] Univ Innsbruck, Fac Chem & Pharm, A-6020 Innsbruck, Austria

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 08期

关键词：

imidazolium salt; ionic liquid; mercury; thione; tribromide; IONIC LIQUIDS; DERIVATIVES; TRIBROMIDE; DIBROMINE; HALOGEN;

D O I：

10.1515/znb-2017-0089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of non-symmetric 1,3-di(alkyloxy)imidazolium salts were synthesized by stepwise alkylation of 1-hydroxyimidazole-3-oxide. The quaternary salts were subsequently functionalized by bromination in 2-position. A 2-azidoimidazolium salt and an imidazoline-2-thione were prepared exemplarily. Crystal structures of two 2-bromo-1-alkyloxy-3-methyloxyimidazolium tribromides and a mercury(II)-thione complex have been determined by X-ray diffraction.

引用

页码：617 / 626

页数：10

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