New formylated phloroglucinol compounds from Eucalyptus globulus foliage

被引：14

作者：

Chenavas, Sophie ^{[1
]}

Fiorini-Puybaret, Christel ^{[2
]}

Joulia, Philippe ^{[2
]}

Larrouquet, Camille ^{[3
]}

Waton, Hugues ^{[1
]}

Martinez, Agathe ^{[4
]}

Casabianca, Herve ^{[1
]}

Fabre, Bernard ^{[2
]}

机构：

[1] Univ Lyon 1, Inst Sci Anal, Dept Serv Cent Anal, UMR CNRS 5280,ENS Lyon, F-69100 Villeurbanne, France

[2] Ctr R&D Pierre Fabre 3, Inst Rech Pierre Fabre, Lab Prod Vegetaux, F-31035 Toulouse 1, France

[3] Ctr Rech Peraudel, Inst Rech Pierre Fabre, Chim Analyt Serv, F-81100 Castres, France

[4] UMR CNRS 6229, UFR Sci Exactes & Nat, Inst Chim Mol Reims, F-51687 Reims, France

来源：

PHYTOCHEMISTRY LETTERS | 2015年 / 11卷

关键词：

Eucalyptus globulus; Myrtacaeae; Formylated phloroglucinolcompounds; Acylphloroglucinols; Macrocarpals; Diformylphloroglucinol; BIOMIMETIC SYNTHESIS; MACROCARPALS H; INHIBITORS; ANTIMALARIAL; DERIVATIVES; EUGLOBAL-G1; GRANDIS; LEAVES;

D O I：

10.1016/j.phytol.2014.11.002

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Two new acylphloroglucinols were isolated from the leaves of Eucalyptus globulus Labill and identified as macrocarpals P (1) and Q (2). Structural elucidations were carried out using conventional 1D and 2D NMR and mass spectrometry together with complementary techniques (UV and IR). Macrocarpal Q was a diastereoisomer of macrocarpal E (3), configuration of which was not precised. Simultaneous isolation of macrocarpals E and Q allowed to determine the configurations of both compounds. The diformylphloroglucinol (4) was also isolated as well as already known compounds grandinol, macrocarpals D, I, L, N, O and am-1. (C) 2014 Phytochemical Society of Europe. Published by Elsevier B.V. All rights reserved.

引用

页码：69 / 73

页数：5

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