Structural Modulation of Two Luminescent Bismuth-organic Frameworks by the Mixed-ligand Synthetic Strategy

被引：7
作者：
Wang Er-Rong [1 ]
Huang Jian-Hao [1 ]
Gu Xiang-Yu [1 ]
Cheng Jian-Wen [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Minist Educ Adv Catalysis Mat, Key Lab, Jinhua 321004, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 07期
基金：
高等学校博士学科点专项科研基金;
关键词：
bismuth; mixed-ligand; luminescence; hydrothermal synthesis; COORDINATION POLYMERS; BUILDING UNITS; COMPLEXES; OXIDE; PRECURSORS; DIVERSITY; CHEMISTRY; SORPTION; LINKERS; BI2O3;
D O I：
10.14102/j.cnki.0254-5861.2011-1471
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reactions of Bi2O3 with pyridine-2,6-dicarboxylic acid (2,6-H(2)pdc) and trimesic acid (H(3)btc)/pyromellitic acid (H(4)pyr) lead to two bismuth-organic frameworks, namely, [Bi(2,6-pdc)(H(2)btc)(H2O)(2)](n) (1) and [Bi-2(2,6-pdc)(2)(H(2)pyr)(H2O)(2)](n) (2). Compound 1 crystallizes in the space group P2(1/c). The dimeric {Bi-2} units are linked by 2,6-pdc(2-) ligands to form 1D chains; Compound 2 exhibits a 2D layered structure with 4(4) network topology by using dimeric {Bi-2} as secondary building units (SBUs). The chains and layers in 1 and 2 are further arranged into 3D supramolecular structures via hydrogen bonding interactions. The compounds emit blue luminescence. Furthermore, the PXRD, TGA, UV-visible and IR spectra were also studied. Compounds 1, 2 represent good examples of using mixed-ligand approach to construct diversity of luminescent bismuth-organic frameworks.
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页码：1100 / 1107
页数：8
相关论文
共 37 条
[1]   Mechanosynthesis of the Metallodrug Bismuth Subsalicylate from Bi2O3 and Structure of Bismuth Salicylate without Auxiliary Organic Ligands [J].
Andre, Vania ;
Hardeman, Andrew ;
Halasz, Ivan ;
Stein, Robin S. ;
Jackson, Graham J. ;
Reid, David G. ;
Duer, Melinda J. ;
Curfs, Caroline ;
Teresa Duarte, M. ;
Friscic, Tomislav .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (34) :7858-7861
[2]   Coordinatively polymeric and monomeric bismuth(III) complexes with pyridine carboxylic acids [J].
Anjaneyulu, O. ;
Prasad, T. K. ;
Swamy, K. C. Kumara .
DALTON TRANSACTIONS, 2010, 39 (08) :1935-1940
[3]   Mixed Linker Strategies for Organic Framework Functionalization [J].
Bunck, David N. ;
Dichtel, William R. .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (03) :818-827
[4]   Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3- Anion [J].
Cao, Zhenbo ;
Yue, Yinchao ;
Yao, Jiyong ;
Lin, Zheshuai ;
He, Ran ;
Hu, Zhanggui .
INORGANIC CHEMISTRY, 2011, 50 (24) :12818-12822
[5]   Bismuth-ferrocene carboxylates: synthesis and structure [J].
Chandrasekhar, Vadapalli ;
Metre, Ramesh K. .
DALTON TRANSACTIONS, 2012, 41 (38) :11684-11691
[6]   Synthesis and Materials Chemistry of Bismuth Tris-(di-i-propylcarbamate): Deposition of Photoactive Bi2O3 Thin Films [J].
Cosham, Samuel D. ;
Hill, Michael S. ;
Horley, Graeme A. ;
Johnson, Andrew L. ;
Jordan, Laura ;
Molloy, Kieran C. ;
Stanton, David C. .
INORGANIC CHEMISTRY, 2014, 53 (01) :503-511
[7]   Bismuth Tri- and Tetraarylcarboxylates: Crystal Structures, In Situ X-ray Diffraction, Intermediates and Luminescence [J].
Feyand, Mark ;
Koeppen, Milan ;
Friedrichs, Gernot ;
Stock, Norbert .
CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (37) :12537-12546
[8]   Automated Diffraction Tomography for the Structure Elucidation of Twinned, Sub-micrometer Crystals of a Highly Porous, Catalytically Active Bismuth Metal-Organic Framework [J].
Feyand, Mark ;
Mugnaioli, Enrico ;
Vermoortele, Frederik ;
Bueken, Bart ;
Dieterich, Johannes M. ;
Reimer, Tim ;
Kolb, Ute ;
de Vos, Dirk ;
Stock, Norbert .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (41) :10373-10376
[9]   Noncentrosymmetric oxides [J].
Halasyamani, PS ;
Poeppelmeier, KR .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :2753-2769
[10]   Metal-organic frameworks (MOFs) based on mixed linker systems: structural diversities towards functional materials [J].
Haldar, Ritesh ;
Maji, Tapas Kumar .
CRYSTENGCOMM, 2013, 15 (45) :9276-9295
1234