Low electric-field driven ultrahigh electrostrains in Sb-substituted (Na,K)NbO3 lead-free ferroelectric ceramics

被引:47
作者
Fu, Jian [1 ]
Zuo, Ruzhong [1 ]
Qi, He [1 ]
Zhang, Chen [1 ]
Li, Jingfeng [2 ]
Li, Longtu [2 ]
机构
[1] Hefei Univ Technol, Sch Mat Sci & Engn, Inst Electro Ceram & Devices, Hefei 230009, Peoples R China
[2] Tsinghua Univ, Dept Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
PHASE-TRANSITION; PIEZOELECTRIC PROPERTIES; STRAINS;
D O I
10.1063/1.4904476
中图分类号
O59 [应用物理学];
学科分类号
摘要
Lead-free (Na0.52K0.48)(Nb1-ySby)O-3 (NKNSy) ferroelectric ceramics were reported to exhibit an ultrahigh electrostrain (dynamic d(33)* (=S/E) of 800-1100 pm/V) in a relatively low driving electric field range (1-4 kV/mm). As evidenced by in-situ synchrotron x-ray diffraction and dielectric measurements, the mechanism of generating large strains was ascribed to both the low-field induced reversible rhombohedral-monoclinic phase transition (1-2 kV/mm) and the enhanced domain switching (2-4 kV/mm) owing to the normal to relaxor phase transformation, which contribute to similar to 62% and similar to 38% of the total strain, respectively. The results indicate that the NKNSy compositions would have excellent potentials for applications of lead-free actuator ceramics. (C) 2014 AIP Publishing LLC.
引用
收藏
页数:4
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