Coordination properties of 3′,5′-cyclic adenosine monophosphate towards copper(II) ions

被引:10
作者
Kaczmarek, P [1 ]
Jezowska-Bojczuk, M [1 ]
机构
[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland
关键词
3; 5; '-cAMP; cyclic nucleotide; copper(II) complex;
D O I
10.1016/j.ica.2004.10.029
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The metal binding ability of 3',5'-cyclic adenosine monophosphate (3',5'-cAMP) molecule using copper(II) ion, as an example of biologically available divalent metal ion, was investigated by potentiometry, EPR and differential spectroscopy (UV-Vis, CD). One complex with stoichiometry Cu(3',5'-cAMP)(+) was found, where Cu(II) ion is bound by N-7 nitrogen of adenine moiety. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:2073 / 2076
页数:4
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