Synthesis, structure and magnetic behavior of new 1D metal-organic coordination polymer with Fe3O core

被引：9

作者：

Yutkin, Maxim P. ^{[1
]}

Zavakhina, Marina S. ^{[1
,2
]}

Virovets, Alexander V. ^{[1
]}

Dybtsev, Danil N. ^{[1
,3
]}

Fedin, Vladimir P. ^{[1
,2
]}

Kusamoto, Tetsuro ^{[4
]}

Nishihara, Hiroshi ^{[4
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] POSTECH, Div Adv Mat Sci, Pohang 790784, South Korea

[4] Univ Tokyo, Dept Chem, Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

来源：

INORGANICA CHIMICA ACTA | 2011年 / 365卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Iron(III) complexes; Coordination polymers; Metal-organic formates; X-ray single-crystal analysis; Magnetic properties; MICROPOROUS MANGANESE FORMATE; DIAMOND FRAMEWORK; NEEL N; FERRIMAGNETISM; TEMPERATURE; ADSORPTION; MN;

D O I：

10.1016/j.ica.2010.10.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New metal-organic coordination polymer, (Me3NH)[Fe-3(mu(3)-O)(mu-HCOO)(8)]center dot DMF (1), was synthesized by heating of Fe(NO3)(3)center dot 9H(2)O and [NH(CH3)(3)]Cl in DMF/HCOOH solution. The single-crystal X-ray structure analysis reveals this compound has 1D anionic framework structure built from Fe3O(mu-HCOO)(6) cluster units linked by formate bridges. Compound 1 was characterized by elemental analysis, IR and TGA. The magnetic susceptibility measurements indicate a strong antiferromagnetic exchange interaction between Fe-III ions in the cluster and intercluster magnetic interaction. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：513 / 516

页数：4

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