In situ formation of a molecular cobalt(iii)/AgCl photocatalyst for visible-light water oxidation

被引：1

作者：

Mogi, Hiroto ^{[1
]}

Okazaki, Megumi ^{[1
,2
]}

Nishioka, Shunta ^{[1
]}

Maeda, Kazuhiko ^{[1
]}

机构：

[1] Tokyo Inst Technol, Sch Sci, Dept Chem, Meguro Ku, 2-12-1 NE 2 Ookayama, Tokyo 1528550, Japan

[2] Japan Soc Promot Sci, Chiyoda Ku, Kojimachi Business Ctr Bldg,5-3-1 Kojimachi, Tokyo 1020083, Japan

来源：

SUSTAINABLE ENERGY & FUELS | 2021年 / 5卷 / 22期

关键词：

AG-AT-AGCL; HIGHLY EFFICIENT; COBALT; EVOLUTION; SYSTEM; NANOCLUSTERS; REDUCTION; PHOSPHATE; CATALYSTS; LATIO2N;

D O I：

10.1039/d1se01075a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hexaamminecobalt(iii) chloride underwent reaction in an aqueous AgNO3 solution containing a buffer base (pH 7-9), producing insoluble AgCl that showed no visible light photoresponse. The resultant molecular Co(iii)/AgCl system showed water oxidation activity under visible light (lambda > 400 nm), approximately five times greater than that of a previously reported CoOx/anatase-TiO2 photocatalyst.

引用

页码：5694 / 5698

页数：6

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