Photo-induced reorganization of molecular packing of amphi-PIC J-aggregates (single J-aggregate spectroscopy)

被引:15
|
作者
Malyukin, YV [1 ]
Sorokin, AV [1 ]
Yefimova, SL [1 ]
Lebedenko, A [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Single Crystals, UA-61001 Kharkov, Ukraine
关键词
amphi-PIC;
D O I
10.1016/j.jlumin.2004.09.082
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Confocal luminescence microscopy has been used to excite and collect luminescence from single amphi-PIC J-aggregate. Two types of J-aggregates have been revealed in the luminescence image: bead-like J-aggregates, which diameter is less than I pm and rod-like ones, which length is about 3 pm and diameter is less than I pm. It has been found that single rod-like and bead-like J-aggregates exhibit different luminescence bands with different decay parameters. At the off-resonance blue tail excitation, the J-aggregate exciton luminescence disappeared within a certain time period and a new band appeared, which cannot be attributed to the monomer emission. The luminescence image shows that the J-aggregate is not destroyed. However, J-aggregate storage in darkness does not recover its exciton luminescence. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:429 / 433
页数:5
相关论文
empty
未找到相关数据