Electron and hole trapping in PbCl2 and PbCl2:Tl crystals

被引:16
作者
Nistor, SV [1 ]
Goovaerts, E
Stefan, M
Schoemaker, D
机构
[1] Univ Instelling Antwerp, Dept Phys, B-2610 Wilrijk, Belgium
[2] Inst Atom Phys, NIMP, R-76900 Bucharest, Romania
关键词
ESR; paramagnetic; centers; irradiation; electron; hole; self-trapping;
D O I
10.1016/S0168-583X(98)00051-2
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Formation of primary paramagnetic point defects under low temperature X-ray irradiation have been studied by ESR and optical absorption in pure and thallium doped PbCl2 single crystals. Besides Pb-2(3+) self-trapped electron (STEL) centers the PbCl2 : Tl crystals exhibit trapped-electron (PbTl)(+)-type centers. Based on production properties of paramagnetic centers it is suggested that besides forming Tl-2 divided by centers the holes are self trapped at pairs of neighbouring Cl- anions resulting in V-k type centers with various orientation and length of the Cl-Cl axis. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:538 / 541
页数:4
相关论文
共 12 条
  • [1] EPR AND LUMINESCENCE OF UV IRRADIATED PBCL2 AND PBBR2 CRYSTALS
    DEGRUIJTER, WC
    KERSSEN, J
    [J]. SOLID STATE COMMUNICATIONS, 1972, 10 (09) : 837 - +
  • [2] LUMINESCENCE OF PBCL2 AND PBBR2 SINGLE-CRYSTALS .2. LUMINESCENCE AND EPR OF UV IRRADIATED CRYSTALS
    DEGRUIJTER, WC
    KERSSEN, J
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1972, 5 (03) : 467 - +
  • [3] DEVRIES KJ, 1963, PHYSICA, V29, P482
  • [4] ELECTRON-SPIN RESONANCE OF A COMPLEX PB+(6P1) DEFECT IN ALKALI-HALIDES
    GOOVAERTS, E
    NISTOR, SV
    SCHOEMAKER, D
    [J]. PHYSICAL REVIEW B, 1983, 28 (07): : 3712 - 3717
  • [5] EPR OF PB+ IONS AND EXCHANGE-COUPLED PB+ ION-PAIRS IN UV-IRRADIATED PBCL2 AND PBBR2 CRYSTALS
    KERSSEN, J
    DEGRUIJT.WC
    VOLGER, J
    [J]. PHYSICA, 1973, 70 (02): : 375 - 396
  • [6] DIRECT OBSERVATION OF ELECTRON SELF-TRAPPING IN PBCL2 CRYSTALS
    NISTOR, SV
    GOOVAERTS, E
    SCHOEMAKER, D
    [J]. PHYSICAL REVIEW B, 1993, 48 (13): : 9575 - 9580
  • [7] Electron self-trapping and photolysis in PbCl2 crystals
    Nistor, SV
    Goovaerts, E
    Schoemaker, D
    [J]. RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1995, 136 (1-4): : 157 - 161
  • [8] Electron trapping in PbCl2:Tl crystals:: The heteronuclear (PbTl)2+ center
    Nistor, SV
    Goovaerts, E
    Schoemaker, D
    [J]. PHYSICAL REVIEW B, 1998, 57 (01): : 1 - 5
  • [9] CONSISTENT ANALYSIS AND TL-2(+) AND PB-2(3+) CENTER ESR PARAMETERS
    NISTOR, SV
    SCHOEMAKER, D
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1995, 190 (02): : 339 - 346
  • [10] OBSERVATION OF HOLE TRAPPED TL2+ CENTERS IN PBCL2-TLCL CRYSTALS
    NISTOR, SV
    STEFAN, M
    URSU, I
    [J]. SOLID STATE COMMUNICATIONS, 1993, 85 (11) : 983 - 985