Electron and hole trapping in PbCl2 and PbCl2:Tl crystals

被引:16
作者
Nistor, SV [1 ]
Goovaerts, E
Stefan, M
Schoemaker, D
机构
[1] Univ Instelling Antwerp, Dept Phys, B-2610 Wilrijk, Belgium
[2] Inst Atom Phys, NIMP, R-76900 Bucharest, Romania
关键词
ESR; paramagnetic; centers; irradiation; electron; hole; self-trapping;
D O I
10.1016/S0168-583X(98)00051-2
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Formation of primary paramagnetic point defects under low temperature X-ray irradiation have been studied by ESR and optical absorption in pure and thallium doped PbCl2 single crystals. Besides Pb-2(3+) self-trapped electron (STEL) centers the PbCl2 : Tl crystals exhibit trapped-electron (PbTl)(+)-type centers. Based on production properties of paramagnetic centers it is suggested that besides forming Tl-2 divided by centers the holes are self trapped at pairs of neighbouring Cl- anions resulting in V-k type centers with various orientation and length of the Cl-Cl axis. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:538 / 541
页数:4
相关论文
共 12 条
[1]   EPR AND LUMINESCENCE OF UV IRRADIATED PBCL2 AND PBBR2 CRYSTALS [J].
DEGRUIJTER, WC ;
KERSSEN, J .
SOLID STATE COMMUNICATIONS, 1972, 10 (09) :837-+
[2]   LUMINESCENCE OF PBCL2 AND PBBR2 SINGLE-CRYSTALS .2. LUMINESCENCE AND EPR OF UV IRRADIATED CRYSTALS [J].
DEGRUIJTER, WC ;
KERSSEN, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1972, 5 (03) :467-+
[3]  
DEVRIES KJ, 1963, PHYSICA, V29, P482
[4]   ELECTRON-SPIN RESONANCE OF A COMPLEX PB+(6P1) DEFECT IN ALKALI-HALIDES [J].
GOOVAERTS, E ;
NISTOR, SV ;
SCHOEMAKER, D .
PHYSICAL REVIEW B, 1983, 28 (07) :3712-3717
[5]   EPR OF PB+ IONS AND EXCHANGE-COUPLED PB+ ION-PAIRS IN UV-IRRADIATED PBCL2 AND PBBR2 CRYSTALS [J].
KERSSEN, J ;
DEGRUIJT.WC ;
VOLGER, J .
PHYSICA, 1973, 70 (02) :375-396
[6]   DIRECT OBSERVATION OF ELECTRON SELF-TRAPPING IN PBCL2 CRYSTALS [J].
NISTOR, SV ;
GOOVAERTS, E ;
SCHOEMAKER, D .
PHYSICAL REVIEW B, 1993, 48 (13) :9575-9580
[7]   Electron self-trapping and photolysis in PbCl2 crystals [J].
Nistor, SV ;
Goovaerts, E ;
Schoemaker, D .
RADIATION EFFECTS AND DEFECTS IN SOLIDS, 1995, 136 (1-4) :157-161
[8]   Electron trapping in PbCl2:Tl crystals:: The heteronuclear (PbTl)2+ center [J].
Nistor, SV ;
Goovaerts, E ;
Schoemaker, D .
PHYSICAL REVIEW B, 1998, 57 (01) :1-5
[9]   CONSISTENT ANALYSIS AND TL-2(+) AND PB-2(3+) CENTER ESR PARAMETERS [J].
NISTOR, SV ;
SCHOEMAKER, D .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1995, 190 (02) :339-346
[10]   OBSERVATION OF HOLE TRAPPED TL2+ CENTERS IN PBCL2-TLCL CRYSTALS [J].
NISTOR, SV ;
STEFAN, M ;
URSU, I .
SOLID STATE COMMUNICATIONS, 1993, 85 (11) :983-985