Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)

被引：18

作者：

Mathur, P

Manimaran, B

Trivedi, R

Hossain, MM

Arabatti, M

机构：

[1] Chemistry Department, Indian Institute of Technology, Powai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 515卷 / 1-2期

关键词：

iron; selenium; methylene; carbonyl; X-ray diffraction; crystal structure;

D O I：

10.1016/0022-328X(95)06056-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From the room temperature reaction of (CO)(9)Fe-3(mu(3)-Se)(2) or (CO)(6)Fe-2(mu-Se-2) with diazomethane, four products were isolated; {(CO)(3)Fe(mu-CH2)Se}(2) (1), (CO)(6)Fe-2(mu-SeCH3)(2) (2), (CO)(6)Fe-2(mu-SeCH2Se) (3) and (CO)(6)Fe-2(mu-SeCH2CH2Se) (4). All four 77 compounds were characterised by IR, H-1, C-13, and Se-77 NMR spectroscopy. Structures of 1, 3 and 4 were established by single crystal X-ray structure analyses.

引用

页码：155 / 162

页数：8

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