Terephthalic Acid Copolyesters Containing Tetramethylcyclobutanediol for High-Performance Plastics

被引：15
作者：
Bhagia, Samarthya [1 ]
Bornani, Kamlesh [2 ]
Ozcan, Soydan [3 ]
Ragauskas, Arthur J. [4 ,5 ,6 ]
机构：
[1] Oak Ridge Natl Lab, Biosci Div, Oak Ridge, TN 37831 USA
[2] Univ Vermont, Dept Mech Engn, Burlington, VT 05405 USA
[3] Oak Ridge Natl Lab, Mfg Sci Div, Oak Ridge, TN 37831 USA
[4] Univ Tennessee, Dept Chem & Biomol Engn, Knoxville, TN 37996 USA
[5] Oak Ridge Natl Lab, Biosci Div, Joint Inst Biol Sci, Oak Ridge, TN 37831 USA
[6] Univ Tennessee, Ctr Renewable Carbon, Dept Forestry Wildlife & Fisheries, Inst Agr, Knoxville, TN 37996 USA
来源：
CHEMISTRYOPEN | 2021年 / 10卷 / 08期
关键词：
polyester; copolyesters; plastic recycling; terephthalic acid; tetramethylcyclobutanediol; ethylene glycol; cyclohexanedimethanol; CHAIN PROPERTIES; POLYESTER; REPLACEMENT; MONOMERS; IMPACT; BPA;
D O I：
10.1002/open.202100171
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
There is a need for high-performance applications for terephthalic acid (TPA) polyesters with high heat resistance, impact toughness, and optical clarity. Bisphenol A (BPA) based polycarbonates and polyarylates have such properties, but BPA is an endocrine disruptor. Therefore, new TPA polyesters that are less hazardous to health and the environment are becoming popular. Tetramethylcyclobutanediol (TMCD) is a difunctional monomer that can be polymerized with TPA and other diols to yield copolyesters with superior properties to conventional TPA polyesters. It has a cyclobutyl ring that makes it more rigid than cyclohexanedimethanol (CHDM) and EG. Thus, TMCD containing TPA copolyesters can have high heat resistance and impact strength. TPA can be made from abundantly available upcycled polyethylene terephthalate (PET). Therefore, this review discusses the synthesis of monomers and copolyesters, the impact of diol composition on material properties, molecular weight, effects of photodegradation, health safety, and substitution of cyclobutane diols for future polyesters.
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收藏
页码：830 / 841
页数：12
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