First structural characterization of a delocalized, mixed-valent, triangular Cu37+ species:: Chemical and electrochemical oxidation of a CuII3(μ3-O) pyrazolate and electronic structure of the oxidation product

被引：37

作者：

Mezei, G

McGrady, JE ^{[1
]}

Raptis, RG

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ Puerto Rico, Dept Chem, San Juan, PR 00931 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 21期

关键词：

D O I：

10.1021/ic050729e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemical or electrochemical one-electron oxidation of the all-Cu '' complex [Cu-3(mu(3)-O)(mu-pz)(3)X-3](2-) leads to its formally Cu '' Cu-2 ''' analogue (pz = pyrazolato anion; X = Cl- and PhCOO-). The X-ray single-crystal structure and density functional theory analysis of the latter agree in revealing the delocalized nature of its mixed-valent CU37+ core.

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页码：7271 / 7273

页数：3

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