The crystal structure of [Na-4(OSiPh(3))(4)(H2O)(3)]

被引：8
作者：
Mommertz, A
Dehnicke, K
Magull, J
机构：
[1] UNIV MARBURG,FACHBEREICH CHEM,D-35032 MARBURG,GERMANY
[2] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 11期
关键词：
sodium triphenylsilanolate hydrate; synthesis; crystal structure;
D O I：
10.1515/znb-1996-1109
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Colourless single crystals of the title compound are obtained from a saturated solution of NaOSiPh(3) in toluene in a humid atmosphere. We have characterized [Na-4(OSiPh(3))(4)(H2O)(3)] by IR spectroscopy and by a crystal structure determination. Space group R3, Z = 6, R = 0.056. Lattice dimensions at -70 degrees C: a = b = 1540.3 pm, c = 2639.6 pm. The compound has the structure of a Na4O4 heterocubane which is only slighty distorted and in which one of the sodium atoms is not hydrated and shows coordination number three.
引用
收藏
页码：1583 / 1586
页数：4
相关论文
共 29 条
[1]  
[Anonymous], 1978, Silicones under the Monogram
[2]   ALPHA-OXYGEN-SUBSTITUTED ORGANOLITHIUM COMPOUNDS AND THEIR CARBENOID NATURE - CALCULATIONS OF THE CONFIGURATIONAL STABILITY AND OF LICH2OH MODEL STRUCTURES, CRYSTAL-STRUCTURE OF DIPHENYL(TRIMETHYLSILYLOXY)METHYLLITHIUM.3 THF, AND THE STEREOCHEMISTRY OF THE (REVERSE) BROOK REARRANGEMENT [J].
BOCHE, G ;
OPEL, A ;
MARSCH, M ;
HARMS, K ;
HALLER, F ;
LOHRENZ, JCW ;
THUMMLER, C ;
KOCH, W .
CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (10) :2265-2273
[3]   INFRARED AND RAMAN-SPECTRA OF PH3SIOH, PH3SNOH AND PH3PBOH [J].
BUENO, WA .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1980, 36 (12) :1059-1064
[4]  
DEHNICKE K, IN PRESS COORD CHEM
[5]  
DIPPEL K, 1987, Z NATURFORSCH B, V42, P1253
[6]  
Dubchak I L, 1983, ZH STRUKT KHIM, V24, P59
[7]  
Dubchak I. L., 1982, ZH STRUKT KHIM, V23, P63
[8]  
ELSBERND CS, 1990, ADV CHEM SER, V224, P245
[9]   ETA-6 BONDING OF BENZENE TO POTASSIUM IN [(C6H6)KOSIME2PH]4 [J].
FUENTES, GR ;
COAN, PS ;
STREIB, WE ;
CAULTON, KG .
POLYHEDRON, 1991, 10 (20-21) :2371-2375
[10]  
GRAALMANN O, 1984, ANGEW CHEM INT EDIT, V23, P891, DOI 10.1002/anie.198408911
123