Catalytic pyrolysis of waste oil into hydrocarbon fuel utilizing cerium oxide catalyst

被引:7
作者
Khalid, Mohamad Arsyad Abdul [1 ]
Abdullah, Nurhayati [2 ]
Ibrahim, Mohamad Nasir Mohamad [1 ]
Taib, Rahmad Mohd [3 ]
Rosid, Salmiah Jamal Mat [4 ]
Shukri, Nurasmat Mohd [5 ]
Yahaya, NoorFatimah [6 ]
Abdullah, Wan Nazwanie Binti Wan [1 ]
机构
[1] Univ Sains Malaysia, Sch Chem Sci, Usm Penang 11800, Malaysia
[2] Univ Sains Malaysia, Sch Phys, Usm Penang 11800, Malaysia
[3] Univ Selangor, Fac Engn & Life Sci, Bestari Jaya 45600, Selangor, Malaysia
[4] Univ Sultan Zainal Abidin, Unisza Sci & Med Fdn Ctr, Gong Badak Campus, Terengganu 21300, Malaysia
[5] Univ Sains Malaysia, Sch Hlth Sci, Kubang Kerian 16150, Kelantan, Malaysia
[6] Univ Sains Malaysia, Adv Med & Dent Inst AMDI, Integrat Med Cluster, Bertam Kepala Batas 13200, Penang, Malaysia
关键词
Waste Lubricant Oil; Fuel; Catalyst; Pyrolysis; Pyrolysis Reactor; ENGINE OIL; LIQUID; CONVERSION; MICROALGAE;
D O I
10.1007/s11814-022-1091-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The depletion of fossil fuels has prompted research into alternative fuels made from regeneration of waste materials. Pyrolysis is a method of converting waste oil into valuable products, such as char, gas, and fuel. This study presents the catalytic pyrolysis of waste oil for producing fuel utilizing cerium oxide, CeO2/Al2O3 and zinc oxide, ZnO/Al2O3 catalyst. The catalyst and oil were characterized using several characterization techniques to find the physicochemical properties of the catalyst and oil. The optimum condition for catalytic pyrolysis was a reaction temperature at 500 degrees C, with the heating rate at 10 degrees C/min, utilizing CeO2/Al2O3 catalyst calcined at 700 degrees C. The catalytic pyrolysis successfully converted the waste oil into fuel and the oil product obtained was 93.01 wt% with a high calorific value (54.2 MJ/kg). The pyrolysis oil is comprised of aliphatic hydrocarbon (C-5-C-15 hydrocarbon) that is within the hydrocarbon range for gasoline and diesel. The oil product was also detected to have a low content of oxygen (3.07 wt%) and sulfur (0.60 wt%), indicating its potential to serve as a cleaner, fuel reducing the sulfur dioxide, SOX formation. The results reveal that pyrolysis reactors have the ability to convert waste oil into hydrocarbon fuel.
引用
收藏
页码:1487 / 1495
页数:9
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