Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes

被引：35

作者：

Black, A ^{[1
]}

Brown, JM ^{[1
]}

Pichon, C ^{[1
]}

机构：

[1] Chem Res Lab, Oxford OX1 3TA, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 42期

关键词：

D O I：

10.1039/b508292g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydroboration of stilbenes and related disubstituted alkenes catalysed by QUINAP complexes may proceed with high enantio- and regioselectivity; rhodium and iridium catalysts give the same product regioisomer but opposite enantiomers.

引用

页码：5284 / 5286

页数：3

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