Stille coupling reactions of functionalized triorganotin halides

被引：1
|
作者：
Thiele, CM [1 ]
Mitchell, TN [1 ]
机构：
[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2004年 / 18卷 / 02期
关键词：
Stille coupling; triorganotin halides; allylic alcohols; fluoride assistance;
D O I：
10.1002/aoc.585
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Convenient conditions for the Stille coupling of halide-bearing triorganotin compounds, which do not normally react under typical Stille reaction conditions, are presented. The coupling of vinylstannanes with allyl bromide using palladium(II) catalysis is accomplished under fluoride assistance to give the substituted 2,5-hexadien-1-ols in Z-configuration. Copyright (C) 2004 John Wiley Sons, Ltd.
引用
收藏
页码：83 / 85
页数：3
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