{μ-6,6′-Dimethoxy-2,2′-[propane-1,3diylbis(nitrilomethylidyne)]diphenolato}dimethanoltrinitratonickel(II)praseodymium(III) methanol disolvate

被引：6

作者：

Liu, Fei ^{[1
]}

Zhang, Fang ^{[1
]}

机构：

[1] Eastern Liaoning Univ, Coll Chem Engn & Mat, Dandong 118003, Liaoning, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808005357

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title dinuclear complex, [NiPr(C19H20N2O4)(NO3)(3)(CH3OH)(2)]center dot 2CH(3)OH, the Ni-II ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol ligands, forming a slightly distorted octahedral geometry. The Pr-III ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from a Schiff base ligand, forming a distorted bicapped square-antiprismatic environment. In the crystal structure, intermolecular O H center dot center dot center dot O hydrogen bonds connect complex molecules and methanol solvent molecules to form (10 (2) over bar) sheets.

引用

页码：M589 / U677

页数：12