Piezoelectricity and Biocompatibility of Flexible ScxAl(1-x)N Thin Films for Compliant MEMS Transducers

被引:8
作者
Algieri, Luciana [1 ,2 ]
Todaro, Maria Teresa [2 ,3 ]
Guido, Francesco [1 ,2 ]
Blasi, Laura [3 ]
Mastronardi, Vincenzo [2 ]
Desmaele, Denis [2 ]
Qualtieri, Antonio [2 ]
Giannini, Cinzia [4 ]
Sibillano, Teresa [4 ]
De Vittorio, Massimo [2 ]
机构
[1] Piezoskin Srl, I-73100 Lecce, Italy
[2] Ist Italiano Tecnol IIT, Ctr Biomol Nanotechnol, I-73010 Arnesono, Italy
[3] CNR, Ist Nanotecnol, I-73100 Lecce, Italy
[4] CNR, Ist Cristallog, I-70126 Bari, Italy
关键词
piezoelectric materials; flexible devices; scandium aluminium nitride films; transducers; micro electro-mechanical systems (MEMS); ENERGY;
D O I
10.1021/acsami.0c00552
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
There is huge research activity in the development of flexible and biocompatible piezoelectric materials for next-generation compliant micro electro-mechanical systems (MEMS) transducers to be exploited in wearable devices and implants. This work reports for the first time on the development of flexible ScxAl(1-x)N films deposited by sputtering technique onto polyimide substrates, assessing their piezoelectricity and biocompatibility. Flexible ScxAl(1-x)N films have been analyzed in terms of morphological, structural, and piezoelectric properties. ScxAl(1-x)N layer exhibits a good surface roughness of 4.40 nm and moderate piezoelectricity with an extracted effective piezoelectric coefficient (d(33)(eff)) value of 1.87 +/- 0.06 pm/V, in good agreement with the diffraction pattern analysis results. Cell viability assay, performed to study the interaction of the ScxAl(1-x)N films with human cell lines, shows that this material does not have significant effects on tested cells. Furthermore, the ScxAl(1-x)N layer, integrated onto a flexible device and analyzed by bending/unbending measurements, shows a peak-to-peak open-circuit voltage (V-OC) of 0.32 V and a short-circuit current (I-SC) of 0.27 mu A, with a generated power of 19.28 nW under optimal resistive load, thus demonstrating the potential of flexible ScxAl(1-x)N films as active layers for next-generation wearable/implantable piezoelectrics.
引用
收藏
页码:18660 / 18666
页数:7
相关论文
共 26 条
[1]   Enhancement of Piezoelectric Response in Scandium Aluminum Nitride Alloy Thin Films Prepared by Dual Reactive Cosputtering [J].
Akiyama, Morito ;
Kamohara, Toshihiro ;
Kano, Kazuhiko ;
Teshigahara, Akihiko ;
Takeuchi, Yukihiro ;
Kawahara, Nobuaki .
ADVANCED MATERIALS, 2009, 21 (05) :593-+
[2]   Flexible Piezoelectric Energy-Harvesting Exploiting Biocompatible AIN Thin Films Grown onto Spin-Coated Polyimide Layers [J].
Algieri, Luciana ;
Todaro, Maria Teresa ;
Guido, Francesco ;
Mastronardi, Vincenzo ;
Desmaele, Denis ;
Qualtieri, Antonio ;
Giannini, Cinzia ;
Sibillano, Teresa ;
De Vittorio, Massimo .
ACS APPLIED ENERGY MATERIALS, 2018, 1 (10) :5203-+
[3]   Tuning the biocompatibility of aluminum nitride [J].
Berg, Nora G. ;
Paskova, Tania ;
Ivanisevic, Albena .
MATERIALS LETTERS, 2017, 189 :1-4
[4]   Synthesis of c-axis oriented AlN thin films on different substrates: A review [J].
Iriarte, G. F. ;
Rodriguez, J. G. ;
Calle, F. .
MATERIALS RESEARCH BULLETIN, 2010, 45 (09) :1039-1045
[5]   Flexible-CMOS and biocompatible piezoelectric AlN material for MEMS applications [J].
Jackson, Nathan ;
Keeney, Lynette ;
Mathewson, Alan .
SMART MATERIALS AND STRUCTURES, 2013, 22 (11)
[6]   Improvement in crystal orientation of AlN thin films prepared on Mo electrodes using AlN interlayers [J].
Kamohara, Toshihiro ;
Akiyama, Morito ;
Uena, Naohiro ;
Kuwano, Noriyuki .
CERAMICS INTERNATIONAL, 2008, 34 (04) :985-989
[7]   Evaluation of Piezoelectric Properties of AlN Using MEMS Resonators [J].
Khine, Lynn ;
Wong, Lionel Y. L. ;
Soon, Jeffrey B. W. ;
Tsai, Julius M. .
NEMS/MEMS TECHNOLOGY AND DEVICES, 2011, 254 :74-77
[8]   Flexible Inorganic Piezoelectric Acoustic Nanosensors for Biomimetic Artificial Hair Cells [J].
Lee, Hyun Soo ;
Chung, Juyong ;
Hwang, Geon-Tae ;
Jeong, Chang Kyu ;
Jung, Youngdo ;
Kwak, Jun-Hyuk ;
Kang, Hanmi ;
Byun, Myunghwan ;
Kim, Wan Doo ;
Hur, Shin ;
Oh, Seung-Ha ;
Lee, Keon Jae .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (44) :6914-6921
[9]   Flexible piezoelectric nanogenerator in wearable self-powered active sensor for respiration and healthcare monitoring [J].
Liu, Z. ;
Zhang, S. ;
Jin, Y. M. ;
Ouyang, H. ;
Zou, Y. ;
Wang, X. X. ;
Xie, L. X. ;
Li, Z. .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2017, 32 (06)
[10]   Piezoelectric ultrasonic transducer based on flexible AIN [J].
Mastronardi, Vincenzo Mariano ;
Guido, Francesco ;
Amato, Massimiliano ;
De Vittorio, Massimo ;
Petroni, Simona .
MICROELECTRONIC ENGINEERING, 2014, 121 :59-63