Chalcogen bonding in synthesis, catalysis and design of materials

被引：360

作者：

Mahmudov, Kamran T. ^{[1
,2
,3
]}

Kopylovich, Maximilian N. ^{[1
]}

Guedes da Silva, M. Fatima C. ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Ave Rovisco Pais, P-1049001 Lisbon, Portugal

[2] Baku State Univ, Dept Chem, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan

[3] RUDN Univ, Organ Chem Dept, 6 Miklukho Maklaya Str, Moscow 117198, Russia

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 31期

关键词：

CENTER-DOT-O; NONBONDED ATOMIC CONTACTS; RAY CRYSTAL-STRUCTURE; ELECTRON-RICH; DIVALENT SULFUR; HYDROGEN-BOND; HALOGEN BOND; THEORETICAL INVESTIGATIONS; NONCOVALENT INTERACTIONS; DIRECTIONAL PREFERENCES;

D O I：

10.1039/c7dt01685a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chalcogen bonding is a type of noncovalent interaction in which a covalently bonded chalcogen atom (O, S, Se or Te) acts as an electrophilic species towards a nucleophilic (negative) region(s) in another or in the same molecule. In general, this interaction is strengthened by the presence of an electron-withdrawing group on the electron-acceptor chalcogen atom and upon moving down in the periodic table of elements, from O to Te. Following a short discussion of the phenomenon of chalcogen bonding, this Perspective presents some demonstrative experimental observations in which this bonding is crucial for synthetic transformations, crystal engineering, catalysis and design of materials as synthons/tectons.

引用

页码：10121 / 10138

页数：18

共 191 条

[1]

Adcock N. M., 1972, ADV INORG CHEM RAD, V15, P1

[2] Effects of Charge and Substituent on the S•••N Chalcogen Bond [J].

Adhikari, Upendra ;

Scheiner, Steve .

JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 118 (17) :3183-3192

[3] CHEMISTRY OF HYPERVALENT SULFUR .4. STRUCTURE OF 1-1 ADDUCT OF HECTORS BASE WITH ARYLCYANAMIDES BOND SWITCH ON HYPERVALENT SULFUR [J].

AKIBA, K ;

TSUCHIYA, T ;

INAMOTO, N ;

ONUMA, K ;

NAGASHIMA, N ;

NAKAMURA, A .

CHEMISTRY LETTERS, 1976, (07) :723-726

[4] Influence of the heteroatom on the optoelectronic properties and transistor performance of soluble thiophene-, selenophene- and tellurophene-vinylene copolymers [J].

Al-Hashimi, Mohammed ;

Han, Yang ;

Smith, Jeremy ;

Bazzi, Hassan S. ;

Alqaradawi, Siham Yousuf A. ;

Watkins, Scott E. ;

Anthopoulos, Thomas D. ;

Heeney, Martin .

CHEMICAL SCIENCE, 2016, 7 (02) :1093-1099

[5] Molecular tailoring of spin-transition materials: preparation, crystal structure and magnetism of trifluoromethyl-pyridyl-1,3,2-dithiazolyl [J].

Alberola, Antonio ;

Eisler, Dana J. ;

Harvey, Laura ;

Rawson, Jeremy M. .

CRYSTENGCOMM, 2011, 13 (06) :1794-1796

[6] Topological reaction sites - very strong chalcogen bonds [J].

Alikhani, Esmail ;

Fuster, Franck ;

Madebene, Bruno ;

Grabowski, Slawomir J. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (06) :2430-2442

[7] Co-crystallisation of thiazyl radicals: preparation and crystal structure of [PhCNSSN][C6F5CNSSN] [J].

Allen, Charlotte ;

Haynes, Delia A. ;

Pask, Christopher M. ;

Rawson, Jeremy M. .

CRYSTENGCOMM, 2009, 11 (10) :2048-2050

[8] A cartography of the van der Waals territories [J].

Alvarez, Santiago .

DALTON TRANSACTIONS, 2013, 42 (24) :8617-8636

[9] REMARKS ON GIANT CONDUCTIVITY IN TTF-TCNQ [J].

ANDERSON, PW ;

LEE, PA ;

SAITOH, M .

SOLID STATE COMMUNICATIONS, 1973, 13 (05) :595-598

[10] BONDING BETWEEN NONBONDED SULFUR AND OXYGEN-ATOMS IN SELECTED ORGANIC-MOLECULES (A QUANTUM CHEMICAL STUDY) [J].

ANGYAN, JG ;

POIRIER, RA ;

KUCSMAN, A ;

CSIZMADIA, IG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (08) :2237-2245

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