Structure and magnetic properties of flower-like α-NiS nanostructures

被引:37
作者
Tang, Chunjuan [1 ]
Zang, Chunhe [1 ]
Su, Jianfeng [1 ]
Zhang, Dongmei [1 ]
Li, Guanghai [2 ]
Zhang, Yongsheng [1 ]
Yu, Ke [3 ,4 ]
机构
[1] Luoyang Inst Sci & Technol, Dept Math & Phys, Luoyang 471023, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys, Hefei 230031, Peoples R China
[3] E China Normal Univ, Minist Educ, Key Lab Polar Mat & Devices, Shanghai 200241, Peoples R China
[4] E China Normal Univ, Dept Elect Engn, Shanghai 200241, Peoples R China
关键词
Inorganic compounds; Nanostructures; Chemical synthesis; Magnetic properties; TO-SEMICONDUCTOR TRANSITION; NICKEL SULFIDE; METAL; NANOPARTICLES;
D O I
10.1016/j.apsusc.2010.11.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper we report the structure and magnetic properties of flower-like alpha-NiS nanostructure prepared by a facile one-step hydrothermal method. The flowers consist of polycrystalline nanoflakes, and the nanoflakes are composed of single crystalline nanocrystals with an average size of about 15 nm. The alpha-NiS flowers exhibit the transition from paramagnetism to ferromagnetism with the blocking temperature of about 12 K. The field dependences of the magnetization prove that these flowers demonstrate a coexistence of antiferromagnetism and ferromagnetism at 5K, and exhibit a strong paramagnetic response at temperature higher than 100 K. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:3388 / 3391
页数:4
相关论文
共 22 条
[1]   Novel morphologies of nickel sulfides: nanotubes and nanoneedles derived from rolled nanosheets in a w/o microemulsion [J].
Chen, DL ;
Gao, L .
JOURNAL OF CRYSTAL GROWTH, 2004, 262 (1-4) :554-560
[2]   Large magnetoresistance and field-induced transitions in Ni1-xS [J].
Chen, P ;
Du, YW .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (01) :105-107
[3]   Nickel sulfide and copper sulfide nanocrystal synthesis and polymorphism [J].
Ghezelbash, A ;
Korgel, BA .
LANGMUIR, 2005, 21 (21) :9451-9456
[4]   Size-dependent magnetic properties of nickel nanochains [J].
He, Lin ;
Zheng, Wangzhi ;
Zhou, Wei ;
Du, Honglin ;
Chen, Chinping ;
Guo, Lin .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (03)
[5]   Synthesis of novel nickel sulfide submicrometer hollow spheres [J].
Hu, Y ;
Chen, JF ;
Chen, WM ;
Lin, XH ;
Li, XL .
ADVANCED MATERIALS, 2003, 15 (09) :726-729
[6]   Metal-insulator transitions [J].
Imada, M ;
Fujimori, A ;
Tokura, Y .
REVIEWS OF MODERN PHYSICS, 1998, 70 (04) :1039-1263
[7]   Synthesis of NiS nanoparticles using a sugar-ester nonionic water-in-oil microemulsion [J].
Khiew, PS ;
Huang, NM ;
Radiman, S ;
Ahmad, MS .
MATERIALS LETTERS, 2004, 58 (05) :762-767
[8]   Magnetic nanoparticles:: Synthesis, protection, functionalization, and application [J].
Lu, An-Hui ;
Salabas, E. L. ;
Schueth, Ferdi .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (08) :1222-1244
[9]   Magnetic phase diagram and metal-insulator transition of NiS2-xSex [J].
Matsuura, M ;
Hiraka, H ;
Yamada, K ;
Endoh, Y .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2000, 69 (05) :1503-1508
[10]  
NEEL L, 1961, CR HEBD ACAD SCI, V252, P4075