Relativistic effects in gas-phase ion chemistry: An experimentalist's view

被引：284
作者：
Schwarz, H [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, Sekr C4, D-10623 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 37期
关键词：
bond activation; ligand effects; methane functionalization; oxidation states; relativistic effects;
D O I：
10.1002/anie.200300572
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：4442 / 4454
页数：13
相关论文
共 167 条
[91]  
MUSAEV DG, 1993, ISRAEL J CHEM, V33, P307
[92]   THEORETICAL-STUDY OF ETHYLENE NOBLE-METAL COMPLEXES [J].
NICOLAS, G ;
SPIEGELMANN, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5410-5419
[93]   MY SEARCH FOR CARBOCATIONS AND THEIR ROLE IN CHEMISTRY (NOBEL LECTURE) [J].
OLAH, GA .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14) :1393-1405
[94]   Pt+-catalyzed oxidation of methane: Theory and experiment [J].
Pavlov, M ;
Blomberg, MRA ;
Siegbahn, PEM ;
Wesendrup, R ;
Heinemann, C ;
Schwarz, H .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (08) :1567-1579
[95]   MECHANISM AND ENERGETICS FOR DEHYDROGENATION OF METHANE BY GASEOUS IRIDIUM IONS [J].
PERRY, JK ;
OHANESSIAN, G ;
GODDARD, WA .
ORGANOMETALLICS, 1994, 13 (05) :1870-1877
[96]  
PITZER KS, 1979, ACCOUNTS CHEM RES, V12, P272
[97]   Spin forbidden chemical reactions of transition metal compounds. New ideas and new computational challenges [J].
Poli, R ;
Harvey, JN .
CHEMICAL SOCIETY REVIEWS, 2003, 32 (01) :1-8
[98]   RELATIVITY AND THE PERIODIC SYSTEM OF ELEMENTS [J].
PYYKKO, P ;
DESCLAUX, JP .
ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (08) :276-281
[99]   PREDICTED LIGAND DEPENDENCE OF THE AU(I) ... AU(I) ATTRACTION IN (XAUPH(3))(2) [J].
PYYKKO, P ;
LI, J ;
RUNEBERG, N .
CHEMICAL PHYSICS LETTERS, 1994, 218 (1-2) :133-138
[100]  
Pyykkö P, 2002, ANGEW CHEM INT EDIT, V41, P3573, DOI 10.1002/1521-3773(20021004)41:19<3573::AID-ANIE3573>3.0.CO
567891011121314