CO2 hydrogenation to high-value products via heterogeneous catalysis

被引：858

作者：

Ye, Run-Ping ^{[1
,2
,3
,4
]}

Ding, Jie ^{[1
,2
,5
]}

Gong, Weibo ^{[1
,2
]}

Argyle, Morris D. ^{[6
]}

Zhong, Qin ^{[5
]}

Wang, Yujun ^{[7
]}

Russell, Christopher K. ^{[1
,2
,8
,9
]}

Xu, Zhenghe ^{[10
]}

Russell, Armistead G. ^{[11
]}

Li, Qiaohong ^{[3
]}

Fan, Maohong ^{[1
,2
,11
,12
]}

Yao, Yuan-Gen ^{[3
]}

机构：

[1] Univ Wyoming, Dept Chem Engn, Laramie, WY 82071 USA

[2] Univ Wyoming, Dept Petr Engn, Laramie, WY 82071 USA

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China

[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[5] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

[6] Brigham Young Univ, Dept Chem Engn, 330 EB, Provo, UT 84602 USA

[7] Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China

[8] Stanford Univ, Dept Civil Engn, Stanford, CA 94305 USA

[9] Stanford Univ, Dept Environm Engn, Stanford, CA 94305 USA

[10] Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Guangdong, Peoples R China

[11] Georgia Inst Technol, Sch Civil & Environm Engn, Mason Bldg,790 Atlantic Dr, Atlanta, GA 30332 USA

[12] Univ Wyoming, Sch Energy Resources, Laramie, WY 82071 USA

来源：

NATURE COMMUNICATIONS | 2019年 / 10卷 / 1期

关键词：

FISCHER-TROPSCH SYNTHESIS; CARBON-DIOXIDE HYDROGENATION; METAL-ORGANIC FRAMEWORKS; CU BIMETALLIC CATALYSTS; METHANOL SYNTHESIS; LIGHT OLEFINS; SELECTIVE CONVERSION; ARTIFICIAL-INTELLIGENCE; HIGHER ALCOHOLS; ALLOY CATALYSTS;

D O I：

10.1038/s41467-019-13638-9

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Recently, carbon dioxide capture and conversion, along with hydrogen from renewable resources, provide an alternative approach to synthesis of useful fuels and chemicals. People are increasingly interested in developing innovative carbon dioxide hydrogenation catalysts, and the pace of progress in this area is accelerating. Accordingly, this perspective presents current state of the art and outlook in synthesis of light olefins, dimethyl ether, liquid fuels, and alcohols through two leading hydrogenation mechanisms: methanol reaction and Fischer-Tropsch based carbon dioxide hydrogenation. The future research directions for developing new heterogeneous catalysts with transformational technologies, including 3D printing and artificial intelligence, are provided.

引用

页数：15

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