Transition metal M(II) complexes with isonicotinic acid 2-(9-anthrylmethylene)-hydrazide

被引：38

作者：

Dianu, Mariana Loredana ^{[1
]}

Kriza, Angela ^{[1
]}

Stanica, Nicolae ^{[2
]}

Musuc, Adina Magdalena ^{[2
]}

机构：

[1] Univ Bucharest, Fac Chem, Dept Inorgan Chem, Bucharest 020464, Romania

[2] Romanian Acad, Ilie Murgulescu Inst Phys Chem, Bucharest 060021, Romania

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2010年 / 75卷 / 11期

关键词：

IR spectra; isonicotinoylhydrazone; Schiff base; transition metal complexes; thermal analysis; SCHIFF-BASE COMPLEXES; ANTIMICROBIAL ACTIVITY; THERMAL-STABILITY; COPPER(II); ZN(II); CU(II); CO(II); IONS; BENZOYLHYDRAZONE; DECOMPOSITION;

D O I：

10.2298/JSC091113121D

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New complexes of isonicotinic acid 2-(9-anthrylmethylene)-hydrazide with Cu(II), Co(II) and Ni(II) have been prepared and characterized by analytical and physico chemical techniques, such as elemental and thermal analyses, magnetic susceptibility and conductivity measurements, and electronic, EPR and IR spectral studies. The infrared spectral studies revealed the bidentate or monodentate nature of the Schiff base in the complexes; the pyridine nitrogen does not participate in the coordination. A tetrahedral geometry is suggested for the nitrate complexes and an octahedral geometry for the others. Thermal studies support the chemical formulation of these complexes.

引用

页码：1515 / 1531

页数：17

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