polymerization of ethylene;
supported titanium catalyst;
prepolymerization;
D O I:
10.14314/polimery.2001.115
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Previously investigated Mg-Al-Ti catalyst has been modified by the application of AlEt3 cocatalyst instead of AlEt2Cl and by the prepolymerization process. Both ways of modifications have increased considerably the activity of the catalyst system studied in ethylene polymerization process. The investigations of active titanium catalyst obtained activated with AlEt3 have revealed the reason for non-linearity of the function of the ethylene polymerization reaction rate versus the catalyst concentration. Additionally, the application of the prepolymerization process has improved the morphology of PE obtained.
机构:
Chevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USAChevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USA
Barr, Jared L.
Kumar, Amit
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h-index: 0
机构:
Univ Kansas, Dept Chem, 1567 Irving Hill Rd, Lawrence, KS 66045 USA
Univ Kansas, Ctr Environm Beneficial Catalysis, 1501 Wakarusa Dr, Lawrence, KS 66047 USAChevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USA
Kumar, Amit
Lionetti, Davide
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h-index: 0
机构:
Univ Kansas, Dept Chem, 1567 Irving Hill Rd, Lawrence, KS 66045 USA
Univ Kansas, Ctr Environm Beneficial Catalysis, 1501 Wakarusa Dr, Lawrence, KS 66047 USAChevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USA
Lionetti, Davide
Cruz, Carlos A.
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h-index: 0
机构:
Chevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USAChevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USA
Cruz, Carlos A.
Blakemore, James D.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Kansas, Dept Chem, 1567 Irving Hill Rd, Lawrence, KS 66045 USA
Univ Kansas, Ctr Environm Beneficial Catalysis, 1501 Wakarusa Dr, Lawrence, KS 66047 USAChevron Phillips Chem Co LP, Phillips 66 Res Ctr, Bartlesville, OK 74003 USA