The growth and fluorescence of phthalocyanine monolayers, thin films and multilayers on hexagonal boron nitride

被引:12
作者
Alkhamisi, Manal [1 ]
Korolkov, Vladimir V. [1 ]
Nizovtsev, Anton S. [2 ,3 ]
Kerfoot, James [1 ]
Taniguchi, Takashi [4 ]
Watanabe, Kenji [4 ]
Besley, Nicholas A. [2 ]
Besley, Elena [2 ]
Beton, Peter H. [1 ]
机构
[1] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
[3] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Academician Lavrentiev Ave 3, Novosibirsk 630090, Russia
[4] Natl Inst Mat Sci, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
基金
英国工程与自然科学研究理事会;
关键词
COBALT-PHTHALOCYANINE; ENERGY-TRANSFER; REAL-SPACE; HYDROGEN; ARRAYS; LEVEL;
D O I
10.1039/c8cc06304d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Free-base phthalocyanine forms distinct interfacial phases and thin films on hexagonal boron nitride including a monolayer arrangement as determined using high resolution atomic force microscopy. The phases reveal significant differences in photoluminescence with an intense peak for monolayer coverages of flat-lying molecules which is red-shifted in agreement with theoretical models.
引用
收藏
页码:12021 / 12024
页数:4
相关论文
共 27 条
[1]   Organic field-effect transistors with high mobility based on copper phthalocyanine [J].
Bao, Z ;
Lovinger, AJ ;
Dodabalapur, A .
APPLIED PHYSICS LETTERS, 1996, 69 (20) :3066-3068
[2]   Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections [J].
Chai, Jeng-Da ;
Head-Gordon, Martin .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (44) :6615-6620
[3]   Phthalocyanines: old dyes, new materials. Putting color in nanotechnology [J].
de la Torre, Gema ;
Claessens, Christian G. ;
Torres, Tomas .
CHEMICAL COMMUNICATIONS, 2007, (20) :2000-2015
[4]   Electrofluorochromism at the single-molecule level [J].
Doppagne, Benjamin ;
Chong, Michael C. ;
Bulou, Herve ;
Boeglin, Alex ;
Scheurer, Fabrice ;
Schull, Guillaume .
SCIENCE, 2018, 361 (6399) :251-254
[6]   Superradiance from Two Dimensional Brick-Wall Aggregates of Dye Molecules: The Role of Size and Shape for the Temperature Dependence [J].
Eisfeld, Alexander ;
Marquardt, Christian ;
Paulheim, Alexander ;
Sokolowski, Moritz .
PHYSICAL REVIEW LETTERS, 2017, 119 (09)
[7]   Optical transition energies of isolated molecular monomers and weakly interacting two-dimensional aggregates [J].
Forker, Roman ;
Dienel, Thomas ;
Krause, Andreas ;
Gruenewald, Marco ;
Meissner, Matthias ;
Kirchhuebel, Tino ;
Groning, Oliver ;
Fritz, Torsten .
PHYSICAL REVIEW B, 2016, 93 (16)
[8]   An organic infrared electroluminescent diode utilizing a phthalocyanine film [J].
Fujii, A ;
Ohmori, Y ;
Yoshino, K .
IEEE TRANSACTIONS ON ELECTRON DEVICES, 1997, 44 (08) :1204-1207
[9]   Supramolecular Assemblies on Surfaces: Nanopatterning, Functionality, and Reactivity [J].
Goronzy, Dominic P. ;
Ebrahim, Maryam ;
Rosei, Federico ;
Arramel ;
Fang, Yuan ;
De Feyter, Steven ;
Tait, Steven L. ;
Wang, Chen ;
Beton, Peter H. ;
Wee, Andrew T. S. ;
Weiss, Paul S. ;
Perepichka, Dmitrii F. .
ACS NANO, 2018, 12 (08) :7445-7481
[10]   Self-Assembly of Cobalt-Phthalocyanine Molecules on Epitaxial Graphene on Ir(111) [J].
Hamalainen, Sampsa K. ;
Stepanova, Mariia ;
Drost, Robert ;
Liljeroth, Peter ;
Lahtinen, Jouko ;
Sainio, Jani .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (38) :20433-20437