Hydrolases in Polymer Chemistry: Chemoenzymatic Approaches to Polymeric Materials

被引：27
作者：
Heise, Andreas [1 ]
Palmans, Anja R. A. [2 ]
机构：
[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
[2] Eindhoven Univ Technol, Lab Mol Sci & Technol, NL-5600 MB Eindhoven, Netherlands
来源：
ENZYMATIC POLYMERISATION | 2010年 / 237卷
关键词：
Block copolymers; Chirality; Dynamic kinetic resolution; Graft copolymer; Kinetic resolution; Polymer networks; RING-OPENING POLYMERIZATION; DYNAMIC KINETIC RESOLUTION; ANTARCTICA LIPASE-B; AMPHIPHILIC DIBLOCK COPOLYMER; ITERATIVE TANDEM CATALYSIS; CANDIDA-ANTARCTICA; EPSILON-CAPROLACTONE; BLOCK-COPOLYMERS; ENANTIOSELECTIVE ESTERIFICATION; CASCADE POLYMERIZATION;
D O I：
10.1007/12_2010_74
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Lipases show high activity in the polymerization of a range of monomers using ring-opening polymerization and polycondensation. The range of polymer structures from this enzymatic polymerization can be further increased by combination with chemical methods. This paper reviews the developments of the last 5-8 years in chemoenzymatic strategies towards polymeric materials. Special emphasis is on the synthesis of polymer architectures like block and graft copolymers and polymer networks. Moreover, the combination of chemical and enzymatic catalysis for the synthesis of unique chiral polymers is highlighted.
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收藏
页码：79 / 113
页数：35
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