Halogen bonding: Recent advances

被引：292

作者：

Fourmigue, Marc ^{[1
]}

机构：

[1] Univ Rennes 1, UMR CNRS 6226, F-35042 Rennes, France

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 2009年 / 13卷 / 3-4期

关键词：

Halogen bond; Hydrogen bond; Crystal engineering; Crystallography; Molecular materials; EXPERIMENTAL ELECTRON-DENSITY; RADICAL-CATION SALTS; TRANS-CINNAMIC ACIDS; LIQUID-CRYSTALS; HYDROGEN-BONDS; MOLECULAR CONDUCTORS; MIXED-VALENCE; X-RAY; 90; K; COMPLEXES;

D O I：

10.1016/j.cossms.2009.05.001

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Halogen bonding (XB), as a directional interaction between covalently bound halogen atoms (XB donor) and Lewis bases (A, XB acceptor), has been recently intensively investigated as a powerful tool in crystal engineering. After a short review on the origin and general features of halogen bonding, current developments towards (i) the elaboration of three-dimensional networks, (ii) the interaction with anionic XB acceptors, (iii) its identification in biological systems and (iv) the formation of liquid crystal phases will be described. Theoretical analyses, statistical studies and experimental electron density determinations converge to describe halogen bonding as a relatively weak structure directing tool, when compared with hydrogen bonding. However, when the halogen atom is strongly activated as in iodoperfluorinated molecules or cationic aromatic systems can halogen bonding act as an efficient and reliable structure directing tool. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：36 / 45

页数：10

共 96 条

[1] Structural competition between hydrogen bonds and halogen bonds [J].

Aakeroey, Christer B. ;

Fasulo, Meg ;

Schultheiss, Nate ;

Desper, John ;

Moore, Curtis .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) :13772-+

[2]

AAKEROY CB, 2007, CHEM COMMUN, P4336

[3] Halogen bonding interactions with the [Mo3S7Cl6]2- cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]•CH3CN [J].

Alberola, Antonio ;

Fourmigue, Marc ;

Gomez-Garcia, Carlos J. ;

Llusar, Rosa ;

Triguero, Sonia .

NEW JOURNAL OF CHEMISTRY, 2008, 32 (07) :1103-1109

[4]

[Anonymous], ATOMS MOLECULES QUAN

[5] Halogen bonds in biological molecules [J].

Auffinger, P ;

Hays, FA ;

Westhof, E ;

Ho, PS .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (48) :16789-16794

[6] The nature of Halogen•••Halide synthons:: Theoretical and crystallographic studies [J].

Awwadi, Firas F. ;

Willett, Roger D. ;

Peterson, Kirk A. ;

Twamley, Brendan .

JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 111 (12) :2319-2328

[7] The nature of halogen ... halogen synthons: Crystallographic and theoretical studies [J].

Awwadi, Firas F. ;

Willett, Roger D. ;

Peterson, Kirk A. ;

Twamley, Brendan .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (35) :8952-8960

[8] The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF•+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4-:: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode [J].

Barres, Anne-Lise ;

El-Ghayoury, Abdelkrim ;

Zorina, Leokadiya V. ;

Canadell, Enric ;

Auban-Senzier, Pascale ;

Batail, Patrick .

CHEMICAL COMMUNICATIONS, 2008, (19) :2194-2196

[9] The experimental electron density distribution in the complex of (E)-1,2-bis(4-pyridyl) ethylene with 1,4-diiodotetrafluorobenzene at 90 K [J].

Bianchi, R ;

Forni, A ;

Pilati, T .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (07) :1631-1638

[10] Experimental electron density study of the supramolecular aggregation between 4,4′-dipyridyl-N,N′-dioxide and 1,4-diiodotetrafluorobenzene at 90 K [J].

Bianchi, R ;

Forni, A ;

Pilati, T .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2004, 60 :559-568

← 1 2 3 4 5 6 7 8 9 10 →