Synthesis, crystal structure and magnetic property of diiron complex [Fe(phen)3][Fe2OCl6]•2CH3CN

被引：7
|
作者：
Yan, B
Chen, ZD [1 ]
Wang, SX
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Appl, Beijing 100871, Peoples R China
[2] Peking Univ, Univ Hong Kong, Joint Lab Rare Earth Mat & Bioinorgan Chem, Beijing 100871, Peoples R China
[3] Jining Teachers Coll, Dept Chem, Jining 272125, Peoples R China
来源：
JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2000年 / 47卷 / 06期
关键词：
synthesis; crystal structure; variable-temperature susceptibility; diron complex;
D O I：
10.1002/jccs.200000164
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new diiron complex has been synthesized and characterized by X-ray single crystal structural analysis: [Fe-II(phen)(3)] [(Fe2OCl6)-O-III]. 2CH(3)CN. The complex crystallizes in the monoclinic system, space group C2/c, with lattice parameters a = 21.162(4) Angstrom, b = 15.168(3) Angstrom, c = 14.812(3) Angstrom, beta = 112.71 (3)degrees, V = 4385.8(15) Angstrom (3), Dx = 1.543 Mg/m(3), Z = 4. The corresponding variable temperature susceptibility measurement shows that there exists an antiferromagnetic interaction in the complex.
引用
收藏
页码：1211 / 1214
页数：4
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