One-dimensional porous nanofibers of Co3O4 on the carbon matrix from human hair with superior lithium ion storage performance

被引:72
作者
Tan, Yanli [1 ]
Gao, Qiuming [1 ]
Yang, Chunxiao [1 ]
Yang, Kai [1 ]
Tian, Weiqian [1 ]
Zhu, Lihua [1 ]
机构
[1] Beihang Univ, Sch Chem & Environm,Minist Educ, Beijing Key Lab Bioinspired Energy Mat & Devices, Key Lab Bioinspired Smart Interfacial Sci & Techo, Beijing 100191, Peoples R China
基金
美国国家科学基金会;
关键词
ENHANCED ELECTROCHEMICAL PERFORMANCE; MESOPOROUS CO3O4; ANODE MATERIALS; RATE CAPABILITY; GRAPHENE; CAPACITY; BATTERIES; NANOSHEETS; ELECTRODES; NANOTUBES;
D O I
10.1038/srep12382
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
One-dimensional (1D) hierarchical porous nanofibers of Co3O4 possessing of (220) facets on the carbon matrix from human hair (H2@Co3O4) with 20-30 nm in width and 3-5 mu m in length are prepared by a facile solvothermal and calcination approach. The well crystallized small Co3O4 particles with the diameter of about 8-12 nm were closely aggregated together in the nanofibers. Electrochemical analyses show that the first discharge capacity of H2@Co3O4 electrode is 1368 mAh g(-1) at the current density of 0.1 A g(-1) based on the total mass of composite. A high reversible capacity of 916 mAh g(-1) was obtained over 100 cycles at 0.1 A g(-1), presenting a good cycling stability. When cycled at a high current density of 1 and 2 A g(-1), the specific capacity of 659 and 573 mAh g(-1) could be still achieved, respectively, indicating a superior power capability.
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页数:11
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