This paper reported the synthesis of poly((dioxolane-1,3)-g-styrene) and poly (dioxolane-1,3-g-AMM) copolymers. It involves the copolymerization of macromonomers of dioxolane-1,3-omega-oxypropyl-methacryloyl with co-monomers such as methacrylic acid, 2-hydroxy-propylmethacrylate (2-HPMA) and styrene, initiated by azobisiso-buteronitrile (ABIN).