Methoxide of an Anderson-type polyoxometalate and its conversion to a new type of species, [IMo9O32(OH)(OH2)3]4-

被引：12

作者：

Honda, D

Ozeki, T ^{[1
]}

Yagasaki, A

机构：

[1] Kwansei Gakuin Univ, Dept Chem, Sanda 6691337, Japan

[2] Tokyo Inst Technol, Dept Chem & Mat Sci, Tokyo 1528551, Japan

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 26期

关键词：

D O I：

10.1021/ic051351n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A totally new type of polyoxometalate, [IMo9O32(OH)(OH2)(3)](4-), has been synthesized by reacting [IMo6O22(OMe)(2)](3-) with water. The [IMo9O32(OH)(OH2)(3)](4-) anion further transforms into [(IMo7O26)(2)](6-), a molecular oxide that has a rutile core, in dry acetonitrile, while it stays intact for several hours in wet acetonitrile.

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页码：9616 / 9618

页数：3

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