Synthesis of 14-Aryl-14H-Dibenzo[a,j]xanthene Derivatives Using Cu(CH3CN)4PF6 as Catalyst

被引:6
|
作者
Soleimani, Ebrahim [1 ]
Zainali, Mohsen [1 ]
Lotfi, Shahram
机构
[1] Razi Univ, Dept Chem, Kermanshah, Iran
基金
美国国家科学基金会;
关键词
14-aryl-14H-dibenzo[a.j]xanthene; aldehyde; bis-14-aryl-14H-dibenzo[a.j]xanthene; Cu(CH3CN)(4)PF6; solvent-free; beta-naphthol; SOLVENT-FREE CONDITIONS; ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; XANTHENE; 14-ARYL; DIBENZOXANTHENES; 14-ALKYL; FACILE; ACID;
D O I
10.2174/157017811797249399
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple and expedient method for the synthesis of a series of 14-aryl-14H-dibenzo[a.j]xanthenes and bis (14aryl-14H-dibenzo[a,j]xanthenes) is described through a one-pot condensation of beta-naphthol with aryl aldehydes catalyzed by Cu(CH3CN)(4)PF6 under solvent-free conditions. The novel synthesis method offers the advantages of high yields, short reaction times, simplicity and easy workup compared to the conventional method of syntheses.
引用
收藏
页码:573 / 576
页数:4
相关论文
共 50 条
  • [1] Ultrasound Promoted One Pot Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthene Derivatives
    Al-Kadasi, Abdulkarim M. A.
    Nazeruddin, G. M.
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (07) : 3155 - 3157
  • [2] Fluoroboric Acid Adsorbed on Silica-Gel-Catalyzed Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthene Derivatives
    Liu, Yu-Heng
    Tao, Xu-Ye
    Lei, Li-Qin
    Zhang, Zhan-Hui
    SYNTHETIC COMMUNICATIONS, 2009, 39 (04) : 580 - 589
  • [3] An efficient multi-component synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives by AgI nanoparticles
    Safaei-Ghomi, Javad
    Ghasemzadeh, Mohammad Ali
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2015, 19 (06) : 642 - 649
  • [4] Synthesis and in vitro study of 14-aryl-14H-dibenzo[a.j]xanthenes as cytotoxic agents
    Bhattacharya, Asish K.
    Rana, Kalpeshkumar C.
    Mujahid, Mohammad
    Sehar, Irum
    Saxena, Ajit K.
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2009, 19 (19) : 5590 - 5593
  • [5] Heteropolyacid:: An efficient and eco-friendly catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene
    Amini, Mostafa Mohammadpour
    Seyyedhamzeh, Mozhdeh
    Bazgir, Ayoob
    APPLIED CATALYSIS A-GENERAL, 2007, 323 : 242 - 245
  • [6] Synthesis, DNA-binding study, and antioxidant activity of 14-aryl-14H-dibenzo[a,j]xanthene derivatives
    Ilangovan, Andivelu
    Anandhan, Karnambaram
    Prasad, Kaushik Mahabir
    Vijayakumar, Pakkiri
    Renganathan, Rajalingam
    Ananth, Devanesan Arul
    Sivasudha, Thilagar
    MEDICINAL CHEMISTRY RESEARCH, 2015, 24 (01) : 344 - 355
  • [7] Synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives catalysed by expanded graphite under solvent-free condition
    Li, Geng-Chen
    JOURNAL OF CHEMICAL RESEARCH, 2008, (08) : 484 - 485
  • [8] Efficient one-pot synthesis of 14-aryl-14H-dibenzo [a,j]xanthene derivatives promoted by niobium pentachloride
    Bartolomeu, Aloisio de Andrade
    de Menezes, Manoel Lima
    da Silva Filho, Luiz Carlos
    CHEMICAL PAPERS, 2014, 68 (11): : 1593 - 1600
  • [9] Silica Supported Perchloric Acid: An Efficient Catalyst for the Synthesis of 14-Aryl-14H-dibenzo[a,i]xanthene-8,13-diones
    Wu, Li Qiang
    Wu, Yan Fang
    Yang, Chun Guang
    Yang, Li Min
    Yang, Li Juan
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2010, 21 (05) : 941 - 945
  • [10] Silica chloride catalyzed synthesis of 14-aryl-14H-dibenzo[a,i] xanthene-8,13-diones
    Wu, Liqiang
    Zhang, Jiangli
    Fang, Lizhen
    Yang, Chunguang
    Yan, Fulin
    DYES AND PIGMENTS, 2010, 86 (01) : 93 - 96