Synthesis and Applications of Periodate for Fine Chemicals and Important Pharmaceuticals

被引：20

作者：

Arndt, Sebastian ^{[1
]}

Kohlpaintner, Philipp J. ^{[1
]}

Donsbach, Kai ^{[2
]}

Waldvogel, Siegfried R. ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Dept Chem, D-55128 Mainz, Germany

[2] Virginia Commonwealth Univ, Coll Engn, Med All Inst, Richmond, VA 23284 USA

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2022年 / 26卷 / 09期

关键词：

periodate; electrolysis; Malaprade oxidation; Lemieux-Johnson oxidation; active pharmaceutical ingredients; CATALYZED ASYMMETRIC DIHYDROXYLATION; CARBOCYCLIC NUCLEOSIDES (-)-ARISTEROMYCIN; CASCADE CYCLIZATION SYNTHESIS; BETULINIC ACID-DERIVATIVES; NUCLEAR-MAGNETIC-RESONANCE; DOPED DIAMOND ELECTRODES; MONOENIC FATTY-ACIDS; OXIDATIVE CLEAVAGE; ELECTROCHEMICAL OXIDATION; VICINAL HYDROXYLATION;

D O I：

10.1021/acs.oprd.2c00161

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An emerging interest for the application of periodate in the synthesis of active pharmaceutical ingredients (APIs) and for the valorization of renewable feedstock is eminent. However, periodate exhibits a high molecular mass, is expensive compared to other common bulk-oxidizers and is used only reluctantly in tedmical applications. Recently, a new and green electrochemical synthesis was established. The preparation and regeneration method for periodate lowers costs and enables the use of periodate in the synthesis of regulated products. This review will briefly introduce the key innovations in the electrochemical synthesis of periodate and will survey the most important applications of periodate in the production of fine chemicals.

引用

页码：2564 / 2613

页数：50

共 562 条

[41] Aversa R. J., 2016, Patent, Patent No. [WO2016038582A1, 2016038582]
[42] Axt S. D., 2008, Preparation of Nucleosides Ribofuranosyl Pyrimidines, Patent No. [2008045419A1, 2008045419, WO2008045419A1]
[43] Badiger S., 2012, Patent, Patent No. [WO2012-101487A1, 2012101487]
[44] Catalytic epoxidation of olefins and hydroxylation of alkanes with sodium periodate by water-soluble manganese(III)salen
Bahramian, B
Mirkhani, V
Tangestaninejad, S
Moghadam, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 244 (1-2) : 139 - 145
[45] Alkane oxidation by osmium tetroxide
Bales, BC
Brown, P
Dehestani, A
Mayer, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (09) : 2832 - 2833
[46] Bansal V., 2018, An Improved Process for the Preparation of Varenicline and Salt Thereof, Patent No. [WO2018163190A1, 2018163190]
[47] Preparation of betulinic acid derivatives by chemical and biotransformation methods and determination of cytotoxicity against selected cancer cell lines
Baratto, Leopoldo C.
Porsani, Mariana V.
Pimentel, Ida C.
Pereira Netto, Adaucto B.
Paschke, Reinhard
Oliveira, Bras H.
[J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2013, 68 : 121 - 131
[48] Total Synthesis of Cyclomarin A, a Marine Cycloheptapeptide with Anti-Tuberculosis and Anti-Malaria Activity
Barbie, Philipp
Kazmaier, Uli
[J]. ORGANIC LETTERS, 2016, 18 (02) : 204 - 207
[49] Note on the iodates and periodates of the alkali metals and the ammonium radicle
Barker, TV
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1908, 93 : 15 - 17
[50] SYNTHESIS OF NOR-AMBREINOLIDE FROM (+)-CIS-ABIENOL
BARRERO, AF
SANCHEZ, JF
ALVAREZMANZANEDA, EJ
ALTAREJOS, J
MUNOZ, M
HAIDOUR, A
[J]. TETRAHEDRON, 1994, 50 (22) : 6653 - 6662

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