Pulsed DC sputtered DLC based nanocomposite films: controlling growth dynamics, microstructure and frictional properties

被引:6
作者
Shaha, K. P. [1 ]
Pei, Y. T. [1 ]
Chen, C. Q. [1 ]
de Hosson, J. Th M. [1 ]
机构
[1] Univ Groningen, Dept Appl Phys, Mat Innovat Inst M2i, NL-9747 AG Groningen, Netherlands
关键词
Dynamic roughening; Smoothing; Ultralow friction; DLC; Nanocomposite; Pulsed DC sputtering; DIAMOND-LIKE CARBON; COATINGS; DEPOSITION; SURFACES;
D O I
10.1179/175355511X12941605982064
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Surface smoothness of diamond-like carbon based thin films becomes a crucial property for developing nearly frictionless protective coatings. Surface roughness and the dynamic growth behaviour of TiC/a-C nanocomposite films, deposited by non-reactive pulsed DC (p-DC) sputtering of graphite targets, were studied using atomic force microscopy and cross-sectional scanning electron microscopy. Upon increasing the intensity of concurrent ion impingement by raising the frequency of p-DC sputtering, a transition from dynamic roughening to dynamic smoothing was revealed, leading to a transition from a strong columnar to a columnar free microstructure. It was shown that smooth films can be deposited on initial rough surfaces at a higher pulse frequency (350 kHz). Also dense, tough, ultrasmooth and ultralow friction TiC/a-C: H nanocomposite films were successfully deposited on industrial polished steel substrates by reactive p-DC sputtering of Ti targets at 350 kHz frequency in an argon/acetylene atmosphere.
引用
收藏
页码:15 / 19
页数:5
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