Olefin metathesis in nano-sized systems

被引：21

作者：

Astruc, Didier ^{[1
]}

Diallo, Abdou K. ^{[1
]}

Gatard, Sylvain ^{[1
]}

Liang, Liyuan ^{[1
]}

Ornelas, Catia ^{[1
]}

Martinez, Victor ^{[1
]}

Mery, Denise ^{[1
]}

Ruiz, Jaime ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, Inst Mol Sci, UMR 5255, F-33405 Talence, France

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 7卷

关键词：

dendrimer; green chemistry; metathesis; nano-system; water; RING-CLOSING METATHESIS; BOND-DISSOCIATION ENERGIES; C-H ACTIVATION; NOBEL LECTURE; CARBOSILANE DENDRIMERS; SONOGASHIRA REACTION; ROOM-TEMPERATURE; GREEN CHEMISTRY; SUZUKI REACTION; CROSS-LINKING;

D O I：

10.3762/bjoc.7.13

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The interplay between olefin metathesis and dendrimers and other nano systems is addressed in this mini review mostly based on the authors' own contributions over the last decade. Two subjects are presented and discussed: (i) The catalysis of olefin metathesis by dendritic nano-catalysts via either covalent attachment (ROMP) or, more usefully, dendrimer encapsulation - ring closing metathesis (RCM), cross metathesis (CM), enyne metathesis reactions (EYM) - for reactions in water without a co-solvent and (ii) construction and functionalization of dendrimers by CM reactions.

引用

页码：94 / 103

页数：10

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