Synthesis of ZnO nanocrystals in sapphire by ion implantation and vacuum annealing

被引:12
作者
Marques, C.
Franco, N.
Alves, L. C.
da Silva, R. C.
Alves, E.
Safran, G.
McHargue, C. J.
机构
[1] Inst Tecnol & Nucl, Dept Fis, LFI, P-2686953 Sacavem, Portugal
[2] Univ Lisbon, Ctr Fis Nucl, P-1649003 Lisbon, Portugal
[3] Res Inst Tech Phys & Mat Sci, H-1525 Budapest, Hungary
[4] Univ Tennessee, Knoxville, TN 37996 USA
关键词
ion implantation; semiconductors; RBS-C; sapphire; nanoparticles; IBIL;
D O I
10.1016/j.nimb.2007.01.123
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The synthesis of embedded ZnO nanoparticles in m-cut sapphire was achieved through high fluence Zn ion implantation, 0.9 x 10(17) cm(-2) at room temperature, followed by annealing at 1000 degrees C in vacuum. In c-cut samples subjected to similar annealing conditions only buried precipitates of Zn form. TEM results in these samples show a high concentration of faceted precipitates distributed along the c-plane and the presence of Kirkendall voids distributed along the entire implanted region. In both cases a strong loss of Zn is observed upon annealing, which depends on the sapphire host orientation. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:515 / 518
页数:4
相关论文
共 14 条
[1]   Fabrication of ZnO nanoparticles in SiO2 by ion implantation combined with thermal oxidation -: art. no. 013109 [J].
Amekura, H ;
Umeda, N ;
Sakuma, Y ;
Kishimoto, N ;
Buchal, C .
APPLIED PHYSICS LETTERS, 2005, 87 (01)
[2]   Nano-structure study of ZnO thin films on sapphire grown with different temperature conditions [J].
Chin, Shu-Cheng ;
Chi, Chun-Yung ;
Lu, Yen-Cheng ;
Hong, Lin ;
Lin, Yu-Li ;
Jen, Fang-Yi ;
Yang, C. C. ;
Zhang, Bao-Ping ;
Segawa, Yusaburo ;
Ma, Kung-Jen ;
Yang, Jer-Ren .
JOURNAL OF CRYSTAL GROWTH, 2006, 293 (02) :344-350
[3]   High-quality ZnO layers grown by MBE on sapphire [J].
El-Shaer, A ;
Mofor, AC ;
Bakin, A ;
Kreye, M ;
Waag, A .
SUPERLATTICES AND MICROSTRUCTURES, 2005, 38 (4-6) :265-271
[4]   Preferred orientation of ZnO nanoparticles formed by post-thermal annealing zinc implanted silica [J].
Liu, YX ;
Liu, YC ;
Shen, DZ ;
Zhong, GZ ;
Fan, XW ;
Kong, XG ;
Mu, R ;
Henderson, DO .
SOLID STATE COMMUNICATIONS, 2002, 121 (9-10) :531-536
[5]   Influence of annealing atmosphere on the behavior of titanium implanted sapphire [J].
Marques, C ;
Alves, E ;
McHargue, C ;
Ononye, LC ;
Monteiro, T ;
Soares, J ;
Allard, LF .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2002, 191 :644-648
[6]  
MARQUES C, IN PRESS VACUUM
[7]   n-ZnO/p-Si photodiodes fabricated using ion-beam induced isolation technique [J].
Park, CH ;
Lee, JY ;
Im, S ;
Kim, TG .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2003, 206 :432-435
[8]   Synthesis and structures of morphology-controlled ZnO nano- and microcrystals [J].
Peng, WQ ;
Qu, SC ;
Cong, GW ;
Wang, ZG .
CRYSTAL GROWTH & DESIGN, 2006, 6 (06) :1518-1522
[9]  
SMIGELSKAS AD, 1947, T AM I MIN MET ENG, V171, P130
[10]  
Stepanov AL, 2005, REV ADV MATER SCI, V9, P109