Preparation and tribological properties of Ti3C2(OH)2 nanosheets as additives in base oil

被引:141
作者
Zhang, Xianghua [1 ,2 ]
Xue, Maoquan [2 ,3 ]
Yang, Xinghua [3 ]
Wang, Zhiping [3 ]
Luo, Guangsi [3 ]
Huang, Zhide [3 ]
Sui, Xiaoli [3 ]
Li, Changsheng [2 ]
机构
[1] Jiangsu Univ Technol, Sch Mech Engn, Changzhou 213001, Jiangsu, Peoples R China
[2] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Jiangsu, Peoples R China
[3] Changzhou Inst Light Ind Technol, Changzhou 213164, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
TRANSITION-METAL CARBIDES; 2-DIMENSIONAL TI3C2; CARBON MATERIALS; ION BATTERIES; THIN SHEETS; GRAPHENE; TI3ALC2; FAMILY; MXENES; REPRESENTATION;
D O I
10.1039/c4ra13800g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two-dimensional Ti3C2(OH)(2) nanosheets were synthesized by exfoliation of laminated Ti3AlC2 in HF and characterized by X-ray diffractometry, SEM, TEM, and HRTEM. The results indicated that the Ti3C2(OH)(2) compounds had 2D layer-like structures with a thickness of 10-20 nm, and the fabrication process of Ti3C2(OH)(2) nanosheets was discussed on the basis of the experimental facts. The tribological properties of Ti3C2(OH)(2) nanosheets as additives in base oil were investigated using a UMT-2 ball-ondisc tribotester. Under the determinate conditions, the friction coefficient of the base oil containing Ti3C2(OH)(2) nanosheets was lower than that of the base oil under 15 N load with 200 rpm, and decreased with increasing mass fraction of Ti3C2(OH)(2) nanosheets when it was < 1.0 wt%. A combination of sliding friction, and stable tribofilm on the rubbing surface could explain the improved tribological properties of Ti3C2(OH)(2) nanosheets as additives.
引用
收藏
页码:2762 / 2767
页数:6
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