Porous porphyrin-based metal-organic frameworks: synthesis, structure, sorption properties and application prospects

被引：31

作者：

Gorbunova, Yulia G. ^{[1
,2
]}

Enakieva, Yulia Yu. ^{[2
]}

V. Volostnykh, Marina ^{[2
]}

Sinelshchikova, Anna A. ^{[2
]}

Abdulaeva, Inna A. ^{[2
]}

Birin, Kirill P. ^{[2
]}

Tsivadze, Aslan Yu. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninsky Prosp 31, Moscow 119991, Russia

[2] Russian Acad Sci, Frumkin Inst Phys Chem & Elect, 31 Leninsky Prosp 31,Stroenie 4, Moscow 119071, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2022年 / 91卷 / 04期

关键词：

PHOTON UP-CONVERSION; EFFECTIVE PHOTODYNAMIC THERAPY; PHOTOCATALYTIC H-2 PRODUCTION; TRIPLET ENERGY MIGRATION; CARBON-DIOXIDE REDUCTION; METALLOPORPHYRIN FRAMEWORK; HIGHLY EFFICIENT; HETEROGENEOUS CATALYSTS; THIN-FILMS; ELECTROCHEMICAL PROPERTIES;

D O I：

10.1070/RCR5038

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unique properties of porous metal-organic frameworks are responsible for the increasing research interest in the design and synthesis of this type of materials. A general strategy towards targeted design of metal-organic frameworks possessing desired properties is a choice of optimal linkers, which are usually represented by polytopic organic ligands. Porphyrins are promising building blocks for such frameworks due to their tunable physicochemical properties and wide possibilities of macrocycle modification. The achievements of the last decade in the development of synthetic approaches to porphyrin functionalization have promoted fast progress of tetrapyrrole chemistry as the basis of metal-organic frameworks. This review gives analysis of the current literature devoted to the synthesis of porphyrin-based metal-organic frameworks and the prospects for their application in modern materials science. The bibliography includes 262 references.

引用

页数：51

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